Mesoporous alumino silicates synthesized with single molecular precursor (sec-BUO)(2)AlOSi(OEt)(3) as aluminum source
文献类型：期刊论文
| 作者 | Li, Y; Yang, QH; Yang, H; Li, C |
| 刊名 | microporous and mesoporous materials
 |
| 出版日期 | 2006-04-15 |
| 卷号 | 91期号:1-3页码:85-91 |
| 关键词 | mesoporous aluminosilicates void defects low Si/Al ratios acidity |
| 英文摘要 | single molecular precursor bis(sec-butoxy)aluminoxytriethoxysilane [(sec-buo)(2)alosi(oet)(3)] was used as aluminum source for the synthesis of mesoporous aluminosilicates with low si/al ratios from 1.0 to 10.0 via a template-assisted method. the samples with si/ al ratios of 1.0 and 3.0 have wormhole-like pore structure, while the samples with si/al ratios of 5.0 and 10.0 have ordered hexagonal mesoporous structures with extensive void defects amid the nanochannels. ir spectra of pyridine adsorption and nh3-tpd characterizations suggest that the mesoporous alummosilicates have both bronsted and lewis acid sites with medium strength. the amounts of acid sites of the mesoporous aluminosilicates do not run parallel with the concentration of the tetrahedrally coordinated aluminum in the mesoporous framework. (c) 2005 elsevier inc. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | chemistry, applied ; chemistry, physical ; nanoscience & nanotechnology ; materials science, multidisciplinary |
| 研究领域[WOS] | chemistry ; science & technology - other topics ; materials science |
| 关键词[WOS] | tris(tert-butoxy)siloxy complexes ; aluminosilicate mesostructures ; thermal-stability ; sieve mcm-41 ; catalysts ; acidity ; surfactant ; mechanism ; niobium ; mullite |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000236656400012 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/140048]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Y,Yang, QH,Yang, H,et al. Mesoporous alumino silicates synthesized with single molecular precursor (sec-BUO)(2)AlOSi(OEt)(3) as aluminum source[J]. microporous and mesoporous materials,2006,91(1-3):85-91. |
| APA | Li, Y,Yang, QH,Yang, H,&Li, C.(2006).Mesoporous alumino silicates synthesized with single molecular precursor (sec-BUO)(2)AlOSi(OEt)(3) as aluminum source.microporous and mesoporous materials,91(1-3),85-91. |
| MLA | Li, Y,et al."Mesoporous alumino silicates synthesized with single molecular precursor (sec-BUO)(2)AlOSi(OEt)(3) as aluminum source".microporous and mesoporous materials 91.1-3(2006):85-91. |
入库方式： OAI收割
来源：大连化学物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。