Synthesis and thermodynamic properties of a metal-organic framework: [LaCu6(mu-OH)(3)(Gly)(6)im(6)](ClO4)(6)
文献类型:期刊论文
作者 | Lv, Xue-Chuan; Tan, Zhi-Cheng; Gao, Xiao-Han; Zhang, Zhi-Heng; Yang, Li-Ni; Zhao, Jun-Ning; Sun, Li-Xian; Zhang, Tao |
刊名 | thermochimica acta
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出版日期 | 2006-11-15 |
卷号 | 450期号:1-2页码:102-104 |
关键词 | [LaCu6(mu-OH)(3)(Gly)(6)im(6)](ClO4)(6) metal-organic frameworks adiabatic calorimetry heat capacity thermal analysis |
英文摘要 | a metal-organic complex, which has the potential property of absorbing gases, [lacu6(mu-oh)(3)(gly)(6)im(6)](clo4)(6) was synthesized through the self-assembly of la3+, cu2+, glycine (gly) and imidazole (im) in aqueous solution and characterized by ir, element analysis and powder xrd. the molar heat capacity, c-p,c-m, was measured from t = 80 to 390 k with an automated adiabatic calorimeter. the thermodynamic functions [h-t - h-298.15] and [s-t - s298.15] were derived from the heat capacity data with temperature interval of 5 k. the thermal stability of the complex was investigated by differential scanning calorimetry (dsc). (c) 2006 elsevier b.v. all rights reserved. |
WOS标题词 | science & technology ; physical sciences |
类目[WOS] | chemistry, analytical ; chemistry, physical |
研究领域[WOS] | chemistry |
关键词[WOS] | heat-capacities ; adiabatic calorimeter |
收录类别 | ISTP ; SCI |
语种 | 英语 |
WOS记录号 | WOS:000242290300021 |
公开日期 | 2015-11-17 |
源URL | [http://159.226.238.44/handle/321008/140075] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Thermochem Lab, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China |
推荐引用方式 GB/T 7714 | Lv, Xue-Chuan,Tan, Zhi-Cheng,Gao, Xiao-Han,et al. Synthesis and thermodynamic properties of a metal-organic framework: [LaCu6(mu-OH)(3)(Gly)(6)im(6)](ClO4)(6)[J]. thermochimica acta,2006,450(1-2):102-104. |
APA | Lv, Xue-Chuan.,Tan, Zhi-Cheng.,Gao, Xiao-Han.,Zhang, Zhi-Heng.,Yang, Li-Ni.,...&Zhang, Tao.(2006).Synthesis and thermodynamic properties of a metal-organic framework: [LaCu6(mu-OH)(3)(Gly)(6)im(6)](ClO4)(6).thermochimica acta,450(1-2),102-104. |
MLA | Lv, Xue-Chuan,et al."Synthesis and thermodynamic properties of a metal-organic framework: [LaCu6(mu-OH)(3)(Gly)(6)im(6)](ClO4)(6)".thermochimica acta 450.1-2(2006):102-104. |
入库方式: OAI收割
来源:大连化学物理研究所
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