A binuclear isocyanide azadithiolatoiron complex relevant to the active site of Fe-only hydrogenases: Synthesis, structure and electrochemical properties
文献类型：期刊论文
| 作者 | Hou, Jun; Peng, Xiaojun; Liu, Jifeng; Gao, Yunling; Zhao, Xing; Gao, Shang; Han, Keli |
| 刊名 | european journal of inorganic chemistry
 |
| 出版日期 | 2006-11-20 |
| 期号 | 22页码:4679-4686 |
| 关键词 | bioinorganic chemistry density functional calculations hydrogenases iron isocyanide ligands |
| 英文摘要 | an aromatic isocynide-substituted diiron complex 5 has been synthesized as amimic for the active site of fe-only hydrogenases. its structure has been fully characterised by x-ray crystallography. the 4-iodophenylisocyanide ligands in 5 are in the basal positions and are nearly parallel to each other, with pi-pi stacking interactions. four isomeric geometries of complex 5 have been optimized by dft calculations, and the electrochemical properties of 5 have been investigated by cyclic voltammetry in the absence and presence of p-toluenesulfonic acid (hots). analysis of the cyclic voltammetric curve indicates that the reduction event at about -1.43 v is electrocatalytically active to proton reduction. this potential is more positive than that of any functionalized propanedithiolatidiiron complex. (c) woley-vch verlag gmbh & co. kgaa. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, inorganic & nuclear |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | effective core potentials ; iron hydrogenase ; desulfovibrio-desulfuricans ; molecular calculations ; clostridium-pasteurianum ; functional models ; diiron subsite ; chemistry ; evolution ; coordination |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000242551900027 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/140088]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Dalian Univ Technol, State Key Lab Fine Chem, Dalian 116012, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116022, Peoples R China |
| 推荐引用方式 GB/T 7714 | Hou, Jun,Peng, Xiaojun,Liu, Jifeng,et al. A binuclear isocyanide azadithiolatoiron complex relevant to the active site of Fe-only hydrogenases: Synthesis, structure and electrochemical properties[J]. european journal of inorganic chemistry,2006(22):4679-4686. |
| APA | Hou, Jun.,Peng, Xiaojun.,Liu, Jifeng.,Gao, Yunling.,Zhao, Xing.,...&Han, Keli.(2006).A binuclear isocyanide azadithiolatoiron complex relevant to the active site of Fe-only hydrogenases: Synthesis, structure and electrochemical properties.european journal of inorganic chemistry(22),4679-4686. |
| MLA | Hou, Jun,et al."A binuclear isocyanide azadithiolatoiron complex relevant to the active site of Fe-only hydrogenases: Synthesis, structure and electrochemical properties".european journal of inorganic chemistry .22(2006):4679-4686. |
入库方式： OAI收割
来源：大连化学物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。