Synthesis, heat capacity and enthalpy of formation of [Ho-2(L-Glu)(2)(H2O)(8)](ClO4)(4)center dot H2O
文献类型：期刊论文
| 作者 | Wu, XM; Tan, ZC; Lv, XC; Qu, SS |
| 刊名 | thermochimica acta
 |
| 出版日期 | 2006-02-15 |
| 卷号 | 441期号:2页码:199-202 |
| 关键词 | solution-reaction calorimetry complexes of rare earth L-glutamic acid [Ho-2(L-Glu)(2)(H2O)(8)](ClO4)(4)center dot H2O heat capacity standard enthalpy of formation |
| 英文摘要 | a complex of holmium perchlorate coordinated with l-glutamic acid, [ho-2(l-glu)(2)(h2o)(8)](clo4)(4)center dot h2o, was prepared with a purity of 98.96%. the compound was characterized by chemical, elemental and thermal analysis. heat capacities of the compound were determined by automated adiabatic calorimetry from 78 to 370 k. the dehydration temperature is 350 k. the dehydration enthalpy and entropy are 16.34 u mol(-1) and 16.67 j k-1 mol(-1), respectively. the standard enthalpy of formation is -6474.6 kj mol(-1) from reaction calorimetry at 298.15 k. (c) 2005 elsevier b.v. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, analytical ; chemistry, physical |
| 研究领域[WOS] | chemistry |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000235417100016 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/140099]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Thermochem Lab, Dalian 116023, Peoples R China 2.Beijing Inst Petrochem Technol, Dept Chem & Mat Engn, Beijing 102617, Peoples R China 3.Wuhan Univ, Dept Chem, Coll Chem & Mol Sci, Wuhan 430072, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wu, XM,Tan, ZC,Lv, XC,et al. Synthesis, heat capacity and enthalpy of formation of [Ho-2(L-Glu)(2)(H2O)(8)](ClO4)(4)center dot H2O[J]. thermochimica acta,2006,441(2):199-202. |
| APA | Wu, XM,Tan, ZC,Lv, XC,&Qu, SS.(2006).Synthesis, heat capacity and enthalpy of formation of [Ho-2(L-Glu)(2)(H2O)(8)](ClO4)(4)center dot H2O.thermochimica acta,441(2),199-202. |
| MLA | Wu, XM,et al."Synthesis, heat capacity and enthalpy of formation of [Ho-2(L-Glu)(2)(H2O)(8)](ClO4)(4)center dot H2O".thermochimica acta 441.2(2006):199-202. |
入库方式： OAI收割
来源：大连化学物理研究所
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