Catalytic performance of the Sb-V mixed oxide on Sb-V-O/SiO2 catalysts in methane selective oxidation to formaldehyde
文献类型：期刊论文
| 作者 | Zhang, HD; Zhang, J; Sun, KQ; Feng, ZC; Ying, PL; Li, C |
| 刊名 | catalysis letters
 |
| 出版日期 | 2006 |
| 卷号 | 106期号:1-2页码:89-93 |
| 关键词 | methane selective oxidation formaldehyde antimony-vanadium mixed oxide phase transform |
| 英文摘要 | sb-v-o/sio2 catalysts were prepared and investigated in methane selective oxidation with o-2 as oxidant. sb-v-o/sio2 catalysts are active and selective in methane selective oxidation. the formaldehyde yield obtained on sb-v-o/sio2 catalysts is clearly higher than that for vox/sio2 and sbox/sio2 catalysts. a one-pass formaldehyde yield up to 3% was obtained on sb-v-o/sio2 catalysts at 650 degrees c. xrd and uv raman studies showed that the phase of sb-v mixed oxide on sb-v-o/sio2 catalysts transformed with decreasing sb/v ratio from sb2vo5 to sbvo4/vsb1-xo4-1.5x phase. the sb-v mixed oxide in sb2vo5 phase is more active and selective than that in sbvo4/vsb1-xo4-1.5x phase. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, physical |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | direct conversion ; oxygen ; challenge |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000234298700015 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/140106]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, HD,Zhang, J,Sun, KQ,et al. Catalytic performance of the Sb-V mixed oxide on Sb-V-O/SiO2 catalysts in methane selective oxidation to formaldehyde[J]. catalysis letters,2006,106(1-2):89-93. |
| APA | Zhang, HD,Zhang, J,Sun, KQ,Feng, ZC,Ying, PL,&Li, C.(2006).Catalytic performance of the Sb-V mixed oxide on Sb-V-O/SiO2 catalysts in methane selective oxidation to formaldehyde.catalysis letters,106(1-2),89-93. |
| MLA | Zhang, HD,et al."Catalytic performance of the Sb-V mixed oxide on Sb-V-O/SiO2 catalysts in methane selective oxidation to formaldehyde".catalysis letters 106.1-2(2006):89-93. |
入库方式： OAI收割
来源：大连化学物理研究所
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