Calculation of chemical, material, and heat equilibrium for ethylbenzene synthesis through alkylation of dilute ethylene with liquid benzene via catalytic phase exchange method
文献类型：期刊论文
| 作者 | Zhao Xuesong; Liu Shenglin; Chen Fucun; Liu Weicheng; Wang Qingxia; Xu Longya |
| 刊名 | chinese journal of catalysis
 |
| 出版日期 | 2006-09-01 |
| 卷号 | 27期号:9页码:762-766 |
| 关键词 | benzene ethylene alkylation ethylbenzene phase exchange equilibrium calculation |
| 英文摘要 | the chemical, material, and heat equilibrium of ethylbenzene. synthesis through alkylation of dilute ethylene with benzene via catalysis and a gas phase-liquid phase exchange method was analyzed and calculated. the isothermal temperature increase is 175.6 degrees c under the conditions of 1 mol/h ethylene, 4 mol/h n-2, 3 mol/ h benzene, 185 degrees c, and 2.0 mpa. the calculation values of temperature increase, ethylene conversion, and ethylbenzene selectivity are in agreement with the experimental results. in the upper section of the reactor, after the heat exchange of fresh benzene of 35 degrees c with the out gas mixture of 202.6 degrees c from the reaction section, the equilibrium temperature of the system is 185.9 degrees c, which is 0.9 degrees c higher than the reaction temperature. however i in the bottom section of the reactor, when dilute ethylene of 35 degrees c mixes with the liquid products of 202.6 degrees c, the equilibrium temperature is only 153.5 degrees c. this is because dilute ethylene needs a lot of heat energy to make the products from the liquid phase to the gas phase. only when the dilute ethylene temperature is increased to 523 degrees c or 91.5 kj heat energy is added, the equilibrium temperature can reach 185 degrees c. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | chemistry, applied ; chemistry, physical ; engineering, chemical |
| 研究领域[WOS] | chemistry ; engineering |
| 关键词[WOS] | fcc off-gas |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000241169700004 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/140137]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Liaoning, Peoples R China 2.CNPC Fushun Petrochem, Fushun 113004, Liaoning, Peoples R China 3.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhao Xuesong,Liu Shenglin,Chen Fucun,et al. Calculation of chemical, material, and heat equilibrium for ethylbenzene synthesis through alkylation of dilute ethylene with liquid benzene via catalytic phase exchange method[J]. chinese journal of catalysis,2006,27(9):762-766. |
| APA | Zhao Xuesong,Liu Shenglin,Chen Fucun,Liu Weicheng,Wang Qingxia,&Xu Longya.(2006).Calculation of chemical, material, and heat equilibrium for ethylbenzene synthesis through alkylation of dilute ethylene with liquid benzene via catalytic phase exchange method.chinese journal of catalysis,27(9),762-766. |
| MLA | Zhao Xuesong,et al."Calculation of chemical, material, and heat equilibrium for ethylbenzene synthesis through alkylation of dilute ethylene with liquid benzene via catalytic phase exchange method".chinese journal of catalysis 27.9(2006):762-766. |
入库方式： OAI收割
来源：大连化学物理研究所
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