Orientation and motion of water molecules at air/water interface
文献类型：期刊论文
| 作者 | Gan, W; Wu, D; Zhang, Z; Guo, Y; Wang, HF |
| 刊名 | chinese journal of chemical physics
 |
| 出版日期 | 2006-02-27 |
| 卷号 | 19期号:1页码:20-24 |
| 关键词 | air/water interface water molecules orientation and motion |
| 英文摘要 | here we report a quantitative study of the orientational structure and motion of water molecule at the air/water interface. analysis of sum frequency generation (sfg) vibrational peak of the free o-h stretching band at 3700 cm(-1) in four experimental configurations showed that orientational motion of water molecule at air/water interface is libratory within a limited angular range. the free oh bond of the interfacial water molecule is tilted around 33 degrees from the interface normal and the orientational distribution or motion width is less than 15 degrees. this picture is significantly different from the previous conclusion that the interfacial water molecule orientation varies over a broad range within the ultrafast vibrational relaxation time, the only direct experimental study concluded for ultrafast and broad orientational motion of a liquid interface by wei et al. (phys. rev. lett. 86, 4799, (2001)) using single sfg experimental configuration. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | physics, atomic, molecular & chemical |
| 研究领域[WOS] | physics |
| 关键词[WOS] | sum-frequency generation ; hydrogen-bond dynamics ; surface-adsorption layers ; liquid-vapor interface ; x-ray reflectivity ; vibrational spectroscopy ; theoretical-analysis ; spectrum ; simulations ; energetics |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000236175100006 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/140168]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Inst Chem, State Key Lab Mol React Dynam, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Gan, W,Wu, D,Zhang, Z,et al. Orientation and motion of water molecules at air/water interface[J]. chinese journal of chemical physics,2006,19(1):20-24. |
| APA | Gan, W,Wu, D,Zhang, Z,Guo, Y,&Wang, HF.(2006).Orientation and motion of water molecules at air/water interface.chinese journal of chemical physics,19(1),20-24. |
| MLA | Gan, W,et al."Orientation and motion of water molecules at air/water interface".chinese journal of chemical physics 19.1(2006):20-24. |
入库方式： OAI收割
来源：大连化学物理研究所
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