Hydrogen desorption kinetics of amorphous Mg0.9Ti0.1Ni1-xPdx (x=0, 0.05, 0.1 and 0.15) electrode alloys
文献类型：期刊论文
| 作者 | Tian Qi-feng; Zhang Yao; Tan Zhi-cheng; Xu Fen; Sun Li-xian; Yuan Hua-tang |
| 刊名 | transactions of nonferrous metals society of china
 |
| 出版日期 | 2006-08-01 |
| 卷号 | 16期号:4页码:747-752 |
| 关键词 | hydrogen desorption kinetics potentiostatic discharge three-dimensional diffusion activation energy hydrogen storage alloys |
| 英文摘要 | the amorphous mg0.9ti0.1ni1-xpdx (x = 0, 0.05, 0.1, 0.15) hydrogen storage alloys were prepared by mechanical alloying. the hydrogen desorption kinetics of the electrode alloys were studied by potentiostatic discharge experiments and linear polarization measurements. the experimental results show that the three-dimensional diffusion model dominates the hydrogen desorption process of the electrode alloys. the rate constants of hydrogen desorption reaction, which are obtained from a linear fitting of the model equation, increase with temperature. the activation energies of hydrogen desorption were calculated according to the arrhenius equation. the calculated values were 46.2, 24.29, 33.4 and 34.95 kj/mol for x = 0, 0.05, 0.1 and 0.15 of mg0.9ti0.1ni1-xpdx (x = 0, 0.05, 0.1, 0.15) electrode alloys, respectively the exchange current densities were determined by the linear polarization experiments. the variation of exchange current densities with pd content in the alloy electrodes agrees with that of activation energies with pd content. |
| WOS标题词 | science & technology ; technology |
| 类目[WOS] | metallurgy & metallurgical engineering |
| 研究领域[WOS] | metallurgy & metallurgical engineering |
| 关键词[WOS] | dehydriding kinetics ; electrochemical properties ; storage alloys ; hydride ; mg ; ti ; pd ; ternary ; batteries |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000240509600001 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/140175]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China 3.Nankai Univ, Inst New Energy Mat Chem, Tianjin 300071, Peoples R China |
| 推荐引用方式 GB/T 7714 | Tian Qi-feng,Zhang Yao,Tan Zhi-cheng,et al. Hydrogen desorption kinetics of amorphous Mg0.9Ti0.1Ni1-xPdx (x=0, 0.05, 0.1 and 0.15) electrode alloys[J]. transactions of nonferrous metals society of china,2006,16(4):747-752. |
| APA | Tian Qi-feng,Zhang Yao,Tan Zhi-cheng,Xu Fen,Sun Li-xian,&Yuan Hua-tang.(2006).Hydrogen desorption kinetics of amorphous Mg0.9Ti0.1Ni1-xPdx (x=0, 0.05, 0.1 and 0.15) electrode alloys.transactions of nonferrous metals society of china,16(4),747-752. |
| MLA | Tian Qi-feng,et al."Hydrogen desorption kinetics of amorphous Mg0.9Ti0.1Ni1-xPdx (x=0, 0.05, 0.1 and 0.15) electrode alloys".transactions of nonferrous metals society of china 16.4(2006):747-752. |
入库方式： OAI收割
来源：大连化学物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。