Facile synthesis of C-3-symmetric tripodal beta-hydroxy amide ligands and their Ti (IV) complex-catalyzed asymmetric addition of diethylzinc to aldehydes
文献类型:期刊论文
作者 | Fang, Tao; Xu, Jiaxi; Du, Da-Ming |
刊名 | letters in organic chemistry
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出版日期 | 2006-10-01 |
卷号 | 3期号:10页码:780-786 |
关键词 | C-3-symmetry beta-hydroxy amide amino alcohol asymmetric synthesis diethylzinc |
英文摘要 | chiral c-3-symmetric tripodal tris(beta-hydroxy amide) ligands have been conveniently synthesized via the reaction of 1,3,5-benzenctricarboxylic chloride and chiral amino alcohols, and the corresponding tris(amino alcohol) ligands were obtained via the borane reduction of amides. the asymmetric diethylzinc addition to various aldehydes catalyzed by these chiral ligand-ti (iv) complexes gave modest enantioselectivities. |
WOS标题词 | science & technology ; physical sciences |
类目[WOS] | chemistry, organic |
研究领域[WOS] | chemistry |
关键词[WOS] | highly enantioselective addition ; chiral molecular recognition ; amino-alcohols ; organozinc reagents ; aliphatic-aldehydes ; carbonyl-compounds ; allylic oxidation ; diphenylzinc ; derivatives ; reduction |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000242910200011 |
公开日期 | 2015-11-17 |
源URL | [http://159.226.238.44/handle/321008/140226] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | Peking Univ, Coll Chem & Mol Engn, Key Lab Bioorgan Chem & Mol Engn, BNLMS, Beijing 100871, Peoples R China |
推荐引用方式 GB/T 7714 | Fang, Tao,Xu, Jiaxi,Du, Da-Ming. Facile synthesis of C-3-symmetric tripodal beta-hydroxy amide ligands and their Ti (IV) complex-catalyzed asymmetric addition of diethylzinc to aldehydes[J]. letters in organic chemistry,2006,3(10):780-786. |
APA | Fang, Tao,Xu, Jiaxi,&Du, Da-Ming.(2006).Facile synthesis of C-3-symmetric tripodal beta-hydroxy amide ligands and their Ti (IV) complex-catalyzed asymmetric addition of diethylzinc to aldehydes.letters in organic chemistry,3(10),780-786. |
MLA | Fang, Tao,et al."Facile synthesis of C-3-symmetric tripodal beta-hydroxy amide ligands and their Ti (IV) complex-catalyzed asymmetric addition of diethylzinc to aldehydes".letters in organic chemistry 3.10(2006):780-786. |
入库方式: OAI收割
来源:大连化学物理研究所
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