In situ X-ray diffraction study of VOx and MoOx dispersion on Al2O3
文献类型:期刊论文
作者 | Huang, XM; Tang, XF; Xu, YD; Shen, WJ |
刊名 | chinese journal of catalysis
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出版日期 | 2006-04-01 |
卷号 | 27期号:4页码:324-328 |
关键词 | in situ X-ray diffraction vanadium oxide molybdenum oxide alumina supported catalyst dispersion |
英文摘要 | the dispersion of vox and moox on al2o3 was investigated by means of in situ x-ray diffraction. for the vox/al2o3 catalyst prepared by the impregnation method, the precursor of (nh4)(2)[vo(c2o4)(2)] dispersed uniformly on the support. (nh4)(2)[vo(c2o4)(2)] began to decompose at 200 degrees c, the decomposition finished at 400 degrees c, and the obtained vox species dispersed through the hxv2o5 phase. for the vox/al2o3 catalyst prepared by mechanical grinding, although there was an interaction between v2o5 and al2o3, no obvious spontaneous dispersion phenomenon was observed; thus the dispersion of vo, was rather poor as compared with the impregnated catalyst. for the moox/al2o3 catalysts prepared by impregnation and mechanical grinding, the moo3 phase resulted from (nh4)(6)mo2o24 center dot 4h(2)o decomposition was not completely the same, and the contents of (040) and (060) crystal planes were different. |
WOS标题词 | science & technology ; physical sciences ; technology |
类目[WOS] | chemistry, applied ; chemistry, physical ; engineering, chemical |
研究领域[WOS] | chemistry ; engineering |
关键词[WOS] | catalytic-properties ; selective oxidation ; formaldehyde ; support ; oxides |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000237431800010 |
公开日期 | 2015-11-17 |
源URL | [http://159.226.238.44/handle/321008/140234] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Liaoning, Peoples R China |
推荐引用方式 GB/T 7714 | Huang, XM,Tang, XF,Xu, YD,et al. In situ X-ray diffraction study of VOx and MoOx dispersion on Al2O3[J]. chinese journal of catalysis,2006,27(4):324-328. |
APA | Huang, XM,Tang, XF,Xu, YD,&Shen, WJ.(2006).In situ X-ray diffraction study of VOx and MoOx dispersion on Al2O3.chinese journal of catalysis,27(4),324-328. |
MLA | Huang, XM,et al."In situ X-ray diffraction study of VOx and MoOx dispersion on Al2O3".chinese journal of catalysis 27.4(2006):324-328. |
入库方式: OAI收割
来源:大连化学物理研究所
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