Experimental and simulation studies on concentration polarization in H-2 enrichment by highly permeable and selective Pd membranes
文献类型：期刊论文
| 作者 | Zhang, H; Liu, DY; He, MF; Xu, HY; Li, WZ |
| 刊名 | journal of membrane science
 |
| 出版日期 | 2006-04-05 |
| 卷号 | 274期号:1-2页码:83-91 |
| 关键词 | palladium membrane H-2 separation concentration polarization mathematical model NH3 decomposition |
| 英文摘要 | highly efficient pd membranes supported on porous ceramic tubes were synthesized by a modified electroless plating method and utilized in h-2 enrichment from the gas mixture that came from an nh3 cracker. two pd membranes whose permeation properties varied widely had been evaluated at temperatures ranging from 623 to 773 k and under pressures up to 5.06625 x 105 pa (5.0 atm). experimental results revealed that the concentration polarization phenomenon played a determining role in the case of gas separation by the highly permeable and selective membranes. it caused a significant loss in both h-2 yield and purity; and therefore, the separation efficiency of h-2 generation system decreased greatly. a mathematical model was built to describe the concentration polarization phenomena in h-2 enrichment by highly permeable and selective pd membranes under the conditions utilized. in line with the experimental observations, this model accurately predicated the dependency of permeation performance on the operation parameters such as pressure, temperature, feed gas flow rate and permeability. (c) 2005 elsevier b.v. all rights reserved. |
| WOS标题词 | science & technology ; technology ; physical sciences |
| 类目[WOS] | engineering, chemical ; polymer science |
| 研究领域[WOS] | engineering ; polymer science |
| 关键词[WOS] | hydrogen separation ; alloy membranes ; palladium ; permeation ; ammonia ; decomposition ; mixture ; thin |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000236096000008 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/140241]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Grad Sch, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 2.Dalian Univ Technol, Dept Appl Math, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, H,Liu, DY,He, MF,et al. Experimental and simulation studies on concentration polarization in H-2 enrichment by highly permeable and selective Pd membranes[J]. journal of membrane science,2006,274(1-2):83-91. |
| APA | Zhang, H,Liu, DY,He, MF,Xu, HY,&Li, WZ.(2006).Experimental and simulation studies on concentration polarization in H-2 enrichment by highly permeable and selective Pd membranes.journal of membrane science,274(1-2),83-91. |
| MLA | Zhang, H,et al."Experimental and simulation studies on concentration polarization in H-2 enrichment by highly permeable and selective Pd membranes".journal of membrane science 274.1-2(2006):83-91. |
入库方式： OAI收割
来源：大连化学物理研究所
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