Monolithic silica capillary column with coated cellulose tris(3,5-dimethylphenylcarbamate) for capillary electrochromatographic separation of enantiomers
文献类型：期刊论文
| 作者 | Qin, F; Xie, CH; Feng, S; Ou, JJ; Kong, L; Ye, ML; Zou, HF |
| 刊名 | electrophoresis
 |
| 出版日期 | 2006-03-01 |
| 卷号 | 27期号:5-6页码:1050-1059 |
| 关键词 | capillary electrochromatography cellulose tris(3 enantiomer separation monolithic silica capillary column 5-dimethylphenylcarbamate) |
| 英文摘要 | monolithic silica capillary columns were prepared by a sol-gel process in fused-silica capillaries with an inner diameter of 50 mu m and were modified by coating of cellulose tris(3,5-dimethylphenylcarbamate). influences of the factors in the modification process on enantiomer separations were investigated. the prepared columns were used to perform enantionner separations by cec. fifteen and two pairs of enantiomers were separated under aqueous and nonaqueous mobile phases, respectively, and most of them were baseline-separated with very high column efficiencies. the van deemter curve was found flat under high linear velocity of the mobile phase, which indicated favorable kinetic properties of the prepared columns. baseline separation of a pair of enantiomers was achieved in 90 s with high-column efficiency by short-end separation under high voltage. |
| WOS标题词 | science & technology ; life sciences & biomedicine ; physical sciences |
| 类目[WOS] | biochemical research methods ; chemistry, analytical |
| 研究领域[WOS] | biochemistry & molecular biology ; chemistry |
| 关键词[WOS] | chiral stationary-phase ; performance liquid-chromatography ; charged polyacrylamide-gels ; dansyl amino-acids ; packed-capillary ; polysaccharide derivatives ; quinidine functionality ; enantioseparations ; copolymerization ; size |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000236511900014 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/140244]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, Natl Chromatograph Res & Anal Ctr, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Qin, F,Xie, CH,Feng, S,et al. Monolithic silica capillary column with coated cellulose tris(3,5-dimethylphenylcarbamate) for capillary electrochromatographic separation of enantiomers[J]. electrophoresis,2006,27(5-6):1050-1059. |
| APA | Qin, F.,Xie, CH.,Feng, S.,Ou, JJ.,Kong, L.,...&Zou, HF.(2006).Monolithic silica capillary column with coated cellulose tris(3,5-dimethylphenylcarbamate) for capillary electrochromatographic separation of enantiomers.electrophoresis,27(5-6),1050-1059. |
| MLA | Qin, F,et al."Monolithic silica capillary column with coated cellulose tris(3,5-dimethylphenylcarbamate) for capillary electrochromatographic separation of enantiomers".electrophoresis 27.5-6(2006):1050-1059. |
入库方式： OAI收割
来源：大连化学物理研究所
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