Structures and Hydrogen Storage Properties of Mg(45)M(5)Co(50) (M=Zr, Ni, Al) Ternary Alloys by Mechanical Alloying
文献类型：期刊论文
| 作者 | Chu, Hai-Liang1,2; Zhang, Yao1; Sun, Li-Xian1; Tian, Qi-Feng1,2; Xu, Fen1; Zhang, Tao1,2; Yuan, Hua-Tang3 |
| 刊名 | international journal of electrochemical science
 |
| 出版日期 | 2006-05-01 |
| 卷号 | 1期号:1页码:47-54 |
| 关键词 | Mg(45)M(5)Co(50) ternary alloys P-C-T curve Mechanical alloying Hydrogen storage property Structure |
| 英文摘要 | ternary alloys mg(45)m(5)co(50)(m= zr, ni, al) were synthesized by mechanical alloying technique to improve the hydrogen storage properties of mg(50)co(50) binary body centered cubic (bcc) alloy. x-ray diffraction (xrd) revealed that the bragg peaks of these alloys were broadened, which indicated that the crystalline size of these alloys was fully pulverized. both bcc phase and amorphous phase in the ternary alloys were found after ball milling for more than 80 h by transmission electron micrograph (tem). with the increase of ball milling time, however, the bcc phase disappears gradually and the amorphous phase dominated the alloys eventually. pressure-composition-isotherms (p-c-t) measurements showed that these ternary alloys containing bcc phase can absorb hydrogen at 353 k within the hydrogen pressure range of 0 similar to 3 mpa. mg(45)al(5)co(50) alloy had the maximum hydrogen absorption amount (2.0 wt. %) among these ternary alloys. moreover, ternary mg45al5co50 alloy exhibited better hydrogenation kinetics than binary mg(50)co(50) alloy. the former took about 30 h to reach the maximum capacity, which is faster than the latter of 40 h. the third elements ni and zr improve the hydrogen desorption properties of mg(50)co(50) alloy which hardly desorbs any hydrogen. tg analysis showed that mg(45)ni(5)co(50) and mg(45)zr(5)co(50) can desorb hydrogen 0.5 wt. % at 350 k and 1.0 wt. % at 470 k, respectively. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | electrochemistry |
| 研究领域[WOS] | electrochemistry |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000208126200005 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/140252]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Mat & Thermochem Lab, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China 3.Nankai Univ, Ins New Energy Mat Chem, Tianjin 300071, Peoples R China |
| 推荐引用方式 GB/T 7714 | Chu, Hai-Liang,Zhang, Yao,Sun, Li-Xian,et al. Structures and Hydrogen Storage Properties of Mg(45)M(5)Co(50) (M=Zr, Ni, Al) Ternary Alloys by Mechanical Alloying[J]. international journal of electrochemical science,2006,1(1):47-54. |
| APA | Chu, Hai-Liang.,Zhang, Yao.,Sun, Li-Xian.,Tian, Qi-Feng.,Xu, Fen.,...&Yuan, Hua-Tang.(2006).Structures and Hydrogen Storage Properties of Mg(45)M(5)Co(50) (M=Zr, Ni, Al) Ternary Alloys by Mechanical Alloying.international journal of electrochemical science,1(1),47-54. |
| MLA | Chu, Hai-Liang,et al."Structures and Hydrogen Storage Properties of Mg(45)M(5)Co(50) (M=Zr, Ni, Al) Ternary Alloys by Mechanical Alloying".international journal of electrochemical science 1.1(2006):47-54. |
入库方式： OAI收割
来源：大连化学物理研究所
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