Photophysical and photocatalytic properties of novel M2BiNbO7 (M = In and Ga)
文献类型：期刊论文
| 作者 | Luan, Jingfei; Zheng, Shourong; Hao, Xiping; Luan, Guoyou; Wu, Xiaoshan; Zou, Zhigang |
| 刊名 | journal of the brazilian chemical society
 |
| 出版日期 | 2006-11-01 |
| 卷号 | 17期号:7页码:1368-1376 |
| 关键词 | inorganic photocatalysts crystal structure removal of methylene blue dye band structure visible light irradiation |
| 英文摘要 | m2binbo7 ( m = in and ga) were synthesized by solid- state reaction method and their structural and photocatalytic properties were investigated. the results indicated that these compounds crystallize in the pyrochlore-type structure, cubic system with space group fd-3m. in addition, the band gaps of in2binbo7 and ga2binbo7 were estimated to be about 2.52( 5) and 2.57( 8) ev, respectively. for the photocatalytic water splitting reaction, h-2 or o-2 evolution was observed from pure water respectively with m2binbo7 ( m = in and ga) as the photocatalysts under ultraviolet light irradiation. photocatalytic degradation of aqueous methylene blue ( mb) dye over these compounds was further investigated under visible light irradiation. m2binbo7 ( m = in and ga) showed markedly higher catalytic activity compared to p-25 for mb photocatalytic degradation under visible light irradiation. complete removal of aqueous mb was observed after visible light irradiation for 160 min with the ga2binbo7 as the photocatalyst and for 180 min with the in2binbo7 as the photocatalyst. the decrease of the total organic carbon ( toc) and the formation of inorganic products, so42- and no3-, demonstrated the continuous mineralization of aqueous mb during the photocatalytic process. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, multidisciplinary |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | visible-light irradiation ; methylene-blue ; degradation ; water ; photodegradation ; nanoparticles ; pollutants ; titania ; dyes ; red |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000242714700025 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/140258]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Nanjing Univ, Sch Environm, State Key Lab Pollut Control & Resource Reuse, Nanjing 210093, Peoples R China 2.Nanjing Univ, Natl Lab Solid State Microstruct, Nanjing 210093, Peoples R China 3.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Luan, Jingfei,Zheng, Shourong,Hao, Xiping,et al. Photophysical and photocatalytic properties of novel M2BiNbO7 (M = In and Ga)[J]. journal of the brazilian chemical society,2006,17(7):1368-1376. |
| APA | Luan, Jingfei,Zheng, Shourong,Hao, Xiping,Luan, Guoyou,Wu, Xiaoshan,&Zou, Zhigang.(2006).Photophysical and photocatalytic properties of novel M2BiNbO7 (M = In and Ga).journal of the brazilian chemical society,17(7),1368-1376. |
| MLA | Luan, Jingfei,et al."Photophysical and photocatalytic properties of novel M2BiNbO7 (M = In and Ga)".journal of the brazilian chemical society 17.7(2006):1368-1376. |
入库方式： OAI收割
来源：大连化学物理研究所
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