In situ electrochemical FTIR spectroscopy of adsorption and oxidation process of methanol on PtRu/C electrocatalyst
文献类型：期刊论文
| 作者 | Wang Qi; Sun Gong-Quan; Yan Shi-You; Wang Guo-Xiong; Xin Qin; Chen Qing-Song; Li Jun-Tao; Jiang Yan-Xia; Sun Shi-Gang |
| 刊名 | chemical journal of chinese universities-chinese
 |
| 出版日期 | 2006-11-10 |
| 卷号 | 27期号:11页码:2123-2127 |
| 关键词 | direct methanol fuel cell PtRu/C methanol oxidation electrochemistry in situ FTIR |
| 英文摘要 | a modified polyol process was used to prepare pt/c, ptru/c and ru/c electrocatalysts. calculated from xrd patterns, the mean particle size of ptru/c electrocatalyst was 2.2 nm and the percentage of ru allayed was 71%, respectively. adsorption and electro-oxidation progress of methanol on ptru/c electrocatalyst was investigated by in situ ftirs, combined with electrochemical experiments. it is revealed that the activity of ptru/c electrocatalyst for methanol oxidation was much higher than that of pt/c. addition of ru in ptr.u/c electrocatalyst changed the characteristic of methanol adsorption, and ru-oh species could oxidize linear bonded co (col) at a lower potential, thus inhibited the catalyst poisoning. in addition, from ftirs results, col was evidently identified to the main poisonous species and the major product was co2. methyl formate was also identified. based on these results, the mechanism of methanol oxidation was discussed. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, multidisciplinary |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | fuel-cells ; film electrode ; thin-films ; platinum ; co ; catalysts ; electrooxidation ; ruthenium ; alloys ; acid |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000242182500031 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/140296]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China 3.Xiamen Univ, Dept Chem, State Key Lab Phys Chem Solid Surfaces, Xiamen 361005, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang Qi,Sun Gong-Quan,Yan Shi-You,et al. In situ electrochemical FTIR spectroscopy of adsorption and oxidation process of methanol on PtRu/C electrocatalyst[J]. chemical journal of chinese universities-chinese,2006,27(11):2123-2127. |
| APA | Wang Qi.,Sun Gong-Quan.,Yan Shi-You.,Wang Guo-Xiong.,Xin Qin.,...&Sun Shi-Gang.(2006).In situ electrochemical FTIR spectroscopy of adsorption and oxidation process of methanol on PtRu/C electrocatalyst.chemical journal of chinese universities-chinese,27(11),2123-2127. |
| MLA | Wang Qi,et al."In situ electrochemical FTIR spectroscopy of adsorption and oxidation process of methanol on PtRu/C electrocatalyst".chemical journal of chinese universities-chinese 27.11(2006):2123-2127. |
入库方式： OAI收割
来源：大连化学物理研究所
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