Asymmetric Diels-Alder reactions on supported bis(oxazoline) catalysts
文献类型：期刊论文
| 作者 | Wang Hong; Liu Jian; Liu Peng; Yang Qihua; Xiao Jianliang; Li Can |
| 刊名 | chinese journal of catalysis
 |
| 出版日期 | 2006-11-01 |
| 卷号 | 27期号:11页码:946-948 |
| 关键词 | supported catalyst bis(oxazoline) complex Diels-Alder reaction activated silica SBA-15 |
| 英文摘要 | periodic mesoporous ethane-silicas functionalized with sulfonic acid, cesium salts of 12-tungstophosphoric acid, activated silica, and sba-15 have been used as solid supports for the immobilization of the bis(oxazoline) copper (ii) catalyst via non-covalent interactions. these heterogeneous catalysts have been evaluated for the diels-alder reaction between 3-((e)-2-butenoyl)-1,3-oxazolin-2-one and cyclopentadiene. the performance of the catalyst relies on the nature of both the support and the anion on the surface of the support. the small number of the silanol groups on the support leads to poor enantloselectivity when sba-15 is used. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | chemistry, applied ; chemistry, physical ; engineering, chemical |
| 研究领域[WOS] | chemistry ; engineering |
| 关键词[WOS] | mesoporous organosilicas ; heterogeneous catalysts ; homogeneous catalysts ; acid ; enantioselectivity ; complexes ; cyclopropanation ; immobilization ; ligands ; silica |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000242869300004 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/140343]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Liaoning, Peoples R China 2.Univ Liverpool, Dept Chem, Liverpool L69 7ZD, Merseyside, England |
| 推荐引用方式 GB/T 7714 | Wang Hong,Liu Jian,Liu Peng,et al. Asymmetric Diels-Alder reactions on supported bis(oxazoline) catalysts[J]. chinese journal of catalysis,2006,27(11):946-948. |
| APA | Wang Hong,Liu Jian,Liu Peng,Yang Qihua,Xiao Jianliang,&Li Can.(2006).Asymmetric Diels-Alder reactions on supported bis(oxazoline) catalysts.chinese journal of catalysis,27(11),946-948. |
| MLA | Wang Hong,et al."Asymmetric Diels-Alder reactions on supported bis(oxazoline) catalysts".chinese journal of catalysis 27.11(2006):946-948. |
入库方式： OAI收割
来源：大连化学物理研究所
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