Stereodynamics study of the N(S-4)+O-2(X-3 Sigma(-)(g))-> O(P-3)+NO(X-2 Pi) reaction
文献类型：期刊论文
| 作者 | Ma, Jian-Jun; Chen, Mao-Du; Cong, Shu-Lin; Han, Ke-Li |
| 刊名 | chemical physics
 |
| 出版日期 | 2006-09-11 |
| 卷号 | 327期号:2-3页码:529-535 |
| 关键词 | quasiclassical trajectory vector correlations stereodynamics |
| 英文摘要 | the vector correlations between products and reagents for the chemical reaction n(s-4) + o-2(x-3 sigma(-)(g)) -> o(p-3) + no(x-2 pi) are studied using quasiclassical trajectory (qct) method at different collision energies on the lowest (2)a' and (4)a potential energy surfaces (pess) given by sayos et al. [ r. sayos, c. oliva, m. gonzalez, j. chem. phys. 117 (2002) 670]. the results indicate that the rotational polarizations of product no on the two pess present different characters for different collision energies. the product rotational angular momentum j' is not only aligned, but also oriented along the direction perpendicular to the scattering plane on the two pess. on the (2)a' pes, the product no mainly tends to be scattered forward as the collision energy increases. and on the (4)a' pes the product displays a switch from the near isotropic scattering to the forward one with the increase of collision energy. at the same collision energy, the product rotational angular momentum is more strongly aligned on the (4)a' foes than on the (2)a' pes. these differences arise from the different constructions of the two pess. (c) 2006 elsevier b.v. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, physical ; physics, atomic, molecular & chemical |
| 研究领域[WOS] | chemistry ; physics |
| 关键词[WOS] | potential-energy surfaces ; product rotational polarization ; angular-momentum polarization ; n(s-4)+o-2 reaction ; cross-sections ; rate constants ; atmospheric reaction ; ab-initio ; bimolecular reactions ; chemical-reactions |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000240650900039 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/140346]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Dalian Univ Technol, Dept Phys, Dalian 116024, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Ma, Jian-Jun,Chen, Mao-Du,Cong, Shu-Lin,et al. Stereodynamics study of the N(S-4)+O-2(X-3 Sigma(-)(g))-> O(P-3)+NO(X-2 Pi) reaction[J]. chemical physics,2006,327(2-3):529-535. |
| APA | Ma, Jian-Jun,Chen, Mao-Du,Cong, Shu-Lin,&Han, Ke-Li.(2006).Stereodynamics study of the N(S-4)+O-2(X-3 Sigma(-)(g))-> O(P-3)+NO(X-2 Pi) reaction.chemical physics,327(2-3),529-535. |
| MLA | Ma, Jian-Jun,et al."Stereodynamics study of the N(S-4)+O-2(X-3 Sigma(-)(g))-> O(P-3)+NO(X-2 Pi) reaction".chemical physics 327.2-3(2006):529-535. |
入库方式： OAI收割
来源：大连化学物理研究所
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