THE ELECTRONIC ENERGY TRANSFER BETWEEN (CO)-C-12 (A (1)Pi) and (CO)-C-13 (X (1)Sigma(+)) STUDIED BY REMPI SPECTROSCOPY
文献类型：期刊论文
| 作者 | He Jinbao; Sha Guohe; Zhang Xiaoyuan; Bai Jiling; Zhang Cunhao |
| 刊名 | acta physico-chimica sinica
 |
| 出版日期 | 1990 |
| 卷号 | 6期号:5页码:534-540 |
| 英文摘要 | the energy transfer processes between (co)-c-12(a(1)pi) and (co)-c-13(x (1)sigma(+)) were studied at 77 k by using the technique of two-color resonance enhanced multiphoton ionization spectroscopy. in a static cell with a mixture of 0.92 (co)-c-13 + 0.08 (co)-c-12, (co)-c-12 molecules were populated to the a state by 2-photon excitation using an uv dye laser. the (co)-c-13(a) resulted from the collision e-e energy transfer were detected by co(a)-> co(b)-> co+ (x) 2-step ionization using a visible dye laser. the energy transfer processes were found to be very fast with total cross sections of 114 +/- 42, 22 +/- 4, 17 +/- 6 angstrom(2) for (co)-c-12(a) v=1,2,3 respectively. we found that for different vibrational channels, cross section decreases with increasing energy mismatch delta e. another interesting result is that, for the lambda doublet, the production of pi(+) is always larger than that of pi(-). the formation of an intermediate exciplex [occo]* is proposed to explain the experimental results. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, physical |
| 研究领域[WOS] | chemistry |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000207573100006 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/140357]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Acad Sinica, Dalian Inst Chem Phys, Dalian, Peoples R China |
| 推荐引用方式 GB/T 7714 | He Jinbao,Sha Guohe,Zhang Xiaoyuan,et al. THE ELECTRONIC ENERGY TRANSFER BETWEEN (CO)-C-12 (A (1)Pi) and (CO)-C-13 (X (1)Sigma(+)) STUDIED BY REMPI SPECTROSCOPY[J]. acta physico-chimica sinica,1990,6(5):534-540. |
| APA | He Jinbao,Sha Guohe,Zhang Xiaoyuan,Bai Jiling,&Zhang Cunhao.(1990).THE ELECTRONIC ENERGY TRANSFER BETWEEN (CO)-C-12 (A (1)Pi) and (CO)-C-13 (X (1)Sigma(+)) STUDIED BY REMPI SPECTROSCOPY.acta physico-chimica sinica,6(5),534-540. |
| MLA | He Jinbao,et al."THE ELECTRONIC ENERGY TRANSFER BETWEEN (CO)-C-12 (A (1)Pi) and (CO)-C-13 (X (1)Sigma(+)) STUDIED BY REMPI SPECTROSCOPY".acta physico-chimica sinica 6.5(1990):534-540. |
入库方式： OAI收割
来源：大连化学物理研究所
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