Observation of Feshbach resonances in the F+H-2 -> HF+H reaction
文献类型：期刊论文
| 作者 | Qiu, MH; Ren, ZF; Che, L; Dai, DX; Harich, SA; Wang, XY; Yang, XM; Xu, CX; Xie, DQ; Gustafsson, M |
| 刊名 | science
 |
| 出版日期 | 2006-03-10 |
| 卷号 | 311期号:5766页码:1440-1443 |
| 英文摘要 | reaction resonances, or transiently stabilized transition-state structures, have proven highly challenging to capture experimentally. here, we used the highly sensitive h atom rydberg tagging time-of-flight method to conduct a crossed molecular beam scattering study of the f + h-2 --> hf + h reaction with full quantum-state resolution. pronounced forward-scattered hf products in the v' = 2 vibrational state were clearly observed at a collision energy of 0.52 kcal/mol; this was attributed to both the ground and the first excited feshbach resonances trapped in the peculiar hf(v' = 3)-h' vibrationally adiabatic potential, with substantial enhancement by constructive interference between the two resonances. |
| WOS标题词 | science & technology |
| 类目[WOS] | multidisciplinary sciences |
| 研究领域[WOS] | science & technology - other topics |
| 关键词[WOS] | potential-energy surface ; configuration-interaction calculations ; semiclassical reaction probabilities ; differential cross-sections ; f+h-2 reaction ; chemical-reaction ; exact quantum ; reaction dynamics ; transition-state ; molecular-beam |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000236029400042 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/140363]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, State Key Lab Mol React Dynam, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Ctr Theoret Computat Chem, Dalian 116023, Peoples R China 3.Dalian Jiaotong Univ, Dept Phys, Dalian, Peoples R China 4.Nanjing Univ, Dept Chem, Inst Theoret & Computat Chem, Nanjing 210093, Jiangsu, Peoples R China 5.Acad Sinica, Inst Atom & Mol Sci, Taipei, Taiwan 6.Univ Colorado, Dept Chem & Biochem, Boulder, CO 80309 USA 7.Natl Univ Singapore, Dept Computat Sci, Singapore 119260, Singapore |
| 推荐引用方式 GB/T 7714 | Qiu, MH,Ren, ZF,Che, L,et al. Observation of Feshbach resonances in the F+H-2 -> HF+H reaction[J]. science,2006,311(5766):1440-1443. |
| APA | Qiu, MH.,Ren, ZF.,Che, L.,Dai, DX.,Harich, SA.,...&Zhang, DH.(2006).Observation of Feshbach resonances in the F+H-2 -> HF+H reaction.science,311(5766),1440-1443. |
| MLA | Qiu, MH,et al."Observation of Feshbach resonances in the F+H-2 -> HF+H reaction".science 311.5766(2006):1440-1443. |
入库方式： OAI收割
来源：大连化学物理研究所
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