1,2-Migration in rhodium(II) carbene transfer reaction: Remarkable steric effect on migratory aptitude
文献类型：期刊论文
| 作者 | Xiao, Fengping; Wang, Jianbo |
| 刊名 | journal of organic chemistry
 |
| 出版日期 | 2006-07-21 |
| 卷号 | 71期号:15页码:5789-5791 |
| 英文摘要 | a series of diazo carbonyl compounds bearing different substituents have been prepared in order to investigate the steric effect in 1,2-migration reaction of rhodium(ii) carbene. through the investigation on the diazo decomposition of these compounds with rh-2(oac)(4), it was found that the steric effect could dramatically influence the migratory aptitude. in many cases, the steric effect could override the inherent electronic effect of the substituent. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, organic |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | diazo carbonyl-compounds ; acid-catalyzed reactions ; decomposition ; esters ; rearrangement ; condensation ; aldehydes ; kdo |
| 收录类别 | SCI ; IC |
| 语种 | 英语 |
| WOS记录号 | WOS:000239017500049 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/140365]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Peking Univ, BNLMS, Key Lab Bioorgan Chem & Mol Engn, Minist Educ,Coll Chem, Beijing 100871, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xiao, Fengping,Wang, Jianbo. 1,2-Migration in rhodium(II) carbene transfer reaction: Remarkable steric effect on migratory aptitude[J]. journal of organic chemistry,2006,71(15):5789-5791. |
| APA | Xiao, Fengping,&Wang, Jianbo.(2006).1,2-Migration in rhodium(II) carbene transfer reaction: Remarkable steric effect on migratory aptitude.journal of organic chemistry,71(15),5789-5791. |
| MLA | Xiao, Fengping,et al."1,2-Migration in rhodium(II) carbene transfer reaction: Remarkable steric effect on migratory aptitude".journal of organic chemistry 71.15(2006):5789-5791. |
入库方式： OAI收割
来源：大连化学物理研究所
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