Continuous fixed-bed gas-phase hydroformylation over PPh3-modified mesostructured cellular foam-supported Rh catalyst
文献类型：期刊论文
| 作者 | Yan, L; Ding, YJ; Zhu, HJ; Yin, HM; Jiao, GP; Zhao, DY; Lin, LW |
| 刊名 | chinese journal of catalysis
 |
| 出版日期 | 2006 |
| 卷号 | 27期号:1页码:1-3 |
| 关键词 | triphenyl phosphine rhodium mesostructured cellular foam supported catalyst propylene hydroformylation |
| 英文摘要 | siliceous mesostructured cellular foams (mcfs) are a new class of three-dimensional hydrothermally robust materials with ultralarge mesopores. the open system of large pores and the controllable pore size give mcfs unique advantages as catalyst supports. in this paper, mcfs were employed as supports in developing the pph3-rh/mcf catalyst for propylene hydroformylation in a fixed-bed reactor. the pph3-rh/mcf catalyst shows high activity (propylene conversion of 21.6% and butyraldehyde tof of 160.6 h(-1)), high selectivity (n-butyraldehyde/i-butyraldehyde = 10.4), and excellent stability under mild conditions of p = 1.0 mpa, t 393 k, and sv = 2 000 h(-1). |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | chemistry, applied ; chemistry, physical ; engineering, chemical |
| 研究领域[WOS] | chemistry ; engineering |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000235437700001 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/140367]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China 3.Fudan Univ, Dept Chem, Shanghai 200433, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yan, L,Ding, YJ,Zhu, HJ,et al. Continuous fixed-bed gas-phase hydroformylation over PPh3-modified mesostructured cellular foam-supported Rh catalyst[J]. chinese journal of catalysis,2006,27(1):1-3. |
| APA | Yan, L.,Ding, YJ.,Zhu, HJ.,Yin, HM.,Jiao, GP.,...&Lin, LW.(2006).Continuous fixed-bed gas-phase hydroformylation over PPh3-modified mesostructured cellular foam-supported Rh catalyst.chinese journal of catalysis,27(1),1-3. |
| MLA | Yan, L,et al."Continuous fixed-bed gas-phase hydroformylation over PPh3-modified mesostructured cellular foam-supported Rh catalyst".chinese journal of catalysis 27.1(2006):1-3. |
入库方式： OAI收割
来源：大连化学物理研究所
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