State to state to state dynamics of the D+H-2 -> HD+H reaction: Control of transition-state pathways via reagent orientation
文献类型：期刊论文
| 作者 | Zhang, JY; Dai, DX; Wang, CC; Harich, SA; Wang, XY; Yang, XM; Gustafsson, M; Skodje, RT |
| 刊名 | physical review letters
 |
| 出版日期 | 2006-03-10 |
| 卷号 | 96期号:9 |
| 英文摘要 | the influence of reagent rotation on the dynamics of the d+h-2-> hd+h reaction is studied. the state-resolved differential cross section is measured using the rydberg-atom scheme in a crossed beam experiment. it is found that the h-2 rotation has a strong influence on the results. this effect was traced to the selection of the quantum bottleneck states through reagent orientation, thus suggesting a novel strategy to control the transition-state pathways in direct chemical reactions. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | physics, multidisciplinary |
| 研究领域[WOS] | physics |
| 关键词[WOS] | spectral quantization ; cross-sections ; scattering ; distributions ; resonances ; barriers ; rotation ; h+h2 |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000235905700018 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/140369]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Acad Sinica, Inst Atom & Mol Sci, Taipei, Taiwan 2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian, Peoples R China 3.Univ Colorado, Dept Chem & Biochem, Boulder, CO 80309 USA |
| 推荐引用方式 GB/T 7714 | Zhang, JY,Dai, DX,Wang, CC,et al. State to state to state dynamics of the D+H-2 -> HD+H reaction: Control of transition-state pathways via reagent orientation[J]. physical review letters,2006,96(9). |
| APA | Zhang, JY.,Dai, DX.,Wang, CC.,Harich, SA.,Wang, XY.,...&Skodje, RT.(2006).State to state to state dynamics of the D+H-2 -> HD+H reaction: Control of transition-state pathways via reagent orientation.physical review letters,96(9). |
| MLA | Zhang, JY,et al."State to state to state dynamics of the D+H-2 -> HD+H reaction: Control of transition-state pathways via reagent orientation".physical review letters 96.9(2006). |
入库方式： OAI收割
来源：大连化学物理研究所
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