Catalytic activity and characterization of oxygen mobility on PtCe0.75Zr0.25O2 catalyst by isotopic exchange with O-18
文献类型：期刊论文
| 作者 | Lin, R; Inmaculada, RR; Belen, BB; Antonio, GR; Sun, GQ; Xin, Q |
| 刊名 | chinese journal of catalysis
 |
| 出版日期 | 2006-02-01 |
| 卷号 | 27期号:2页码:109-114 |
| 关键词 | platinum cerium oxide zirconium oxide ethanol carbon monoxide oxidation oxygen isotopic exchange temperature-programmed desorption temperature-programmed surface reaction |
| 英文摘要 | the ce0.75zr0.25o2-supported pt catalysts with different pt loadings were prepared by the impregnation method. the results of isotopic exchange of o-18, temperature-programmed surface reaction of ethanol (c2h5oh-tpsr), temperature-programmed desorption of co (co-tpd), and temperature-programmed reduction of h-2(h-2-tpr) show that the pt phase is amorphous and well dispersed on the support surface. the c2h5oh-tpsr and co-tpd results show a good correlation of the amount of desorbed co2 with the catalytic activity for ethanol or co oxidation. the pt/ce0.75zr0.25o2 catalyst has improved activity for ethanol or co oxidation, and the catalytic activity is related to the pt loading. the results of the ethanol or co oxidation and isotopic exchange of o-18 show that the oxygen exchange capacity is responsible for the improved catalytic activity. the sample with the best catalytic activity has the highest surface oxygen diffusion rate. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | chemistry, applied ; chemistry, physical ; engineering, chemical |
| 研究领域[WOS] | chemistry ; engineering |
| 关键词[WOS] | o-xylene ; oxidation ; palladium ; activation ; reduction ; migration ; benzene ; surface ; oxides ; co |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000235990300005 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/140380]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Spanish Council Sci Res, Inst Catalysis & Petrochem, Madrid 28049, Spain 2.Chinese Acad Sci, Dalian Inst Chem Phys, Direct Alcohol Fuel Cell Lab, State Key Lab Catalysis, Dalian 116023, Liaoning, Peoples R China 3.Tongji Univ, Inst Hydrogen Technol, Sch Automot Studies, Shanghai 201804, Peoples R China 4.Natl Univ Distance Educ, Dept Inorgan Chem & Technol, Fac Sci, Madrid 28040, Spain |
| 推荐引用方式 GB/T 7714 | Lin, R,Inmaculada, RR,Belen, BB,et al. Catalytic activity and characterization of oxygen mobility on PtCe0.75Zr0.25O2 catalyst by isotopic exchange with O-18[J]. chinese journal of catalysis,2006,27(2):109-114. |
| APA | Lin, R,Inmaculada, RR,Belen, BB,Antonio, GR,Sun, GQ,&Xin, Q.(2006).Catalytic activity and characterization of oxygen mobility on PtCe0.75Zr0.25O2 catalyst by isotopic exchange with O-18.chinese journal of catalysis,27(2),109-114. |
| MLA | Lin, R,et al."Catalytic activity and characterization of oxygen mobility on PtCe0.75Zr0.25O2 catalyst by isotopic exchange with O-18".chinese journal of catalysis 27.2(2006):109-114. |
入库方式： OAI收割
来源：大连化学物理研究所
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