Vibrations and theoretical calculations of p-methylanisole in the first electronically excited S-1 and ionic ground D-0 states
文献类型：期刊论文
| 作者 | Huang, Jiangou; Tzeng, Wenbih |
| 刊名 | spectrochimica acta part a-molecular and biomolecular spectroscopy
 |
| 出版日期 | 2007-07-01 |
| 卷号 | 67期号:3-4页码:824-829 |
| 关键词 | 1C-R2PI 2C-R2PI MATI vibrations |
| 英文摘要 | one-color (1c), two-color (2c) resonant two-photon ionization (r2pi), and mass analyzed threshold ionization (mati) methods have been applied to study the s <- s-0 transition and threshold ionization of p-methylanisole. the excitation energy of the s <- s-0 transition is determined to be 35,401 +/- 2cm(-1) the adiabatic ionization energy of this molecule is measured to be 63,965 +/- 15 and 63,972 +/- 15 cm(-1) by the 2c-r2pi and mati methods. most of the observed r2pi and mati bands result from the in-plane ring vibrations. the frequencies of vibrations 9b, i and 7a are measured to be 393, 800 and 1168cm(-1) in the s-1 state, and 412, 811 and 1220cm(-1) in the do state, respectively. this indicates the molecular structure in the do state is more rigid than that in the s-1 state. (c) 2006 elsevier b.v. all rights reserved. |
| WOS标题词 | science & technology ; technology |
| 类目[WOS] | spectroscopy |
| 研究领域[WOS] | spectroscopy |
| 关键词[WOS] | threshold ionization spectroscopy ; pulsed-field-ionization ; fluorescence lifetimes ; rydberg states ; ab-initio ; energy ; cation ; photoelectron ; aniline ; benzene |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000247452400041 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/140393]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Cent S Univ, Coll Chem & Chem Engn, Changsha 410083, Peoples R China 2.Chinese Acad Sci, Inst Chem, State Key Lab Mol React Dynam, Beijing 100080, Peoples R China 3.Acad Sinica, Inst Atom & Mol Sci, Taipei 10617, Taiwan |
| 推荐引用方式 GB/T 7714 | Huang, Jiangou,Tzeng, Wenbih. Vibrations and theoretical calculations of p-methylanisole in the first electronically excited S-1 and ionic ground D-0 states[J]. spectrochimica acta part a-molecular and biomolecular spectroscopy,2007,67(3-4):824-829. |
| APA | Huang, Jiangou,&Tzeng, Wenbih.(2007).Vibrations and theoretical calculations of p-methylanisole in the first electronically excited S-1 and ionic ground D-0 states.spectrochimica acta part a-molecular and biomolecular spectroscopy,67(3-4),824-829. |
| MLA | Huang, Jiangou,et al."Vibrations and theoretical calculations of p-methylanisole in the first electronically excited S-1 and ionic ground D-0 states".spectrochimica acta part a-molecular and biomolecular spectroscopy 67.3-4(2007):824-829. |
入库方式： OAI收割
来源：大连化学物理研究所
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