LiBH(4) nanoparticles supported by disordered mesoporous carbon: Hydrogen storage performances and destabilization mechanisms
文献类型：期刊论文
| 作者 | Zhang, Yao; Zhang, Wan-Sheng; Wang, Ai-Qin; Sun, Li-Xian; Fan, Mei-Qiang; Chu, Hai-Liang; Sun, Jun-Cai; Zhang, Tao |
| 刊名 | international journal of hydrogen energy
 |
| 出版日期 | 2007-11-01 |
| 卷号 | 32期号:16页码:3976-3980 |
| 关键词 | LiBH(4) nanoparticles disordered mesoporous carbon hydrogen storage performances destabilization mechanisms |
| 英文摘要 | libh(4) nanoparticles supported by disordered mesoporous carbon cmk-3, denoted as nano-libh(4)/c(mesoporous), were synthesized in the present work. nano-libh(4) in this sample was destabilized significantly, resulting in more favorable latent heat of dehydrogenation (40 kj/mol h(2)), large amount of dehydrogenation capacity (14wt%) below 600 degrees c and reversible capacity of 6.0wt% h(2) at 350 degrees c. it was revealed that such destabilization results from two kinds of mechanisms: nano-dispersion and reaction with mesoporous carbon. both mechanisms exert synergistic effects on the dehydrogenation of nano-libh(4) and reverse hydrogenation. (c) 2007 international association for hydrogen energy. published by elsevier ltd. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | chemistry, physical ; electrochemistry ; energy & fuels |
| 研究领域[WOS] | chemistry ; electrochemistry ; energy & fuels |
| 关键词[WOS] | metal ; borohydride ; mixtures ; hydrides ; release ; imides ; li |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000251463200046 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/140406]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Mat & Thermochem Lab, Dalian 116023, Peoples R China 2.Dalian Maritime Univ, Electromech & Mat Engn Coll, Dalian 116026, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Yao,Zhang, Wan-Sheng,Wang, Ai-Qin,et al. LiBH(4) nanoparticles supported by disordered mesoporous carbon: Hydrogen storage performances and destabilization mechanisms[J]. international journal of hydrogen energy,2007,32(16):3976-3980. |
| APA | Zhang, Yao.,Zhang, Wan-Sheng.,Wang, Ai-Qin.,Sun, Li-Xian.,Fan, Mei-Qiang.,...&Zhang, Tao.(2007).LiBH(4) nanoparticles supported by disordered mesoporous carbon: Hydrogen storage performances and destabilization mechanisms.international journal of hydrogen energy,32(16),3976-3980. |
| MLA | Zhang, Yao,et al."LiBH(4) nanoparticles supported by disordered mesoporous carbon: Hydrogen storage performances and destabilization mechanisms".international journal of hydrogen energy 32.16(2007):3976-3980. |
入库方式： OAI收割
来源：大连化学物理研究所
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