Effect of preparation method and calcination temperature on low-temperature CO oxidation over Co3O4/CeO2 catalyst
文献类型：期刊论文
| 作者 | Shao Jianjun; Zhang Ping; Tang Xingfu; Zhang Baocai; Song Wei; Xu Yide; Shen Wenjie |
| 刊名 | chinese journal of catalysis
 |
| 出版日期 | 2007-02-01 |
| 卷号 | 28期号:2页码:163-169 |
| 关键词 | cobalt oxide ceria carbon monoxide |
| 英文摘要 | co3o4/ceo2 mixed oxides were prepared by coprecipitation-oxidation, homogeneous precipitation, and complexation-combustion methods. the catalysts were used to catalyze low-temperature co oxidation under dry and humid conditions. the co3o4/ceo2 catalyst prepared by the coprecipitation-oxidation method followed by calcination at 538 k exhibited excellent activity and good resistance to water vapor poisoning. remarkably, a co conversion of 99% was achieved at a temperature as low as 196 k and was maintained more than 400 min under the dry condition. when the reaction was carried out at 298 k, a co conversion of 94% was obtained after running the reaction for 2 400 min. even when 3.1% steam was added, a co conversion of 79% could be kept after 2 400 min time-on-stream at 383 k. it is suggested that the strong interaction between co3o4 and ceo2 is closely related to the preparation route and the calcination temperature and plays a crucial role in the co oxidation over the co3o4/ceo2 catalyst. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | chemistry, applied ; chemistry, physical ; engineering, chemical |
| 研究领域[WOS] | chemistry ; engineering |
| 关键词[WOS] | carbon-monoxide oxidation ; cobaltic oxide ; surface ; reactivity ; metal |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000244994000015 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/140417]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Acad Armored Force Engn, Natl Key Lab Remfg, Beijing 100072, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Liaoning, Peoples R China |
| 推荐引用方式 GB/T 7714 | Shao Jianjun,Zhang Ping,Tang Xingfu,et al. Effect of preparation method and calcination temperature on low-temperature CO oxidation over Co3O4/CeO2 catalyst[J]. chinese journal of catalysis,2007,28(2):163-169. |
| APA | Shao Jianjun.,Zhang Ping.,Tang Xingfu.,Zhang Baocai.,Song Wei.,...&Shen Wenjie.(2007).Effect of preparation method and calcination temperature on low-temperature CO oxidation over Co3O4/CeO2 catalyst.chinese journal of catalysis,28(2),163-169. |
| MLA | Shao Jianjun,et al."Effect of preparation method and calcination temperature on low-temperature CO oxidation over Co3O4/CeO2 catalyst".chinese journal of catalysis 28.2(2007):163-169. |
入库方式： OAI收割
来源：大连化学物理研究所
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