trans-(1R,2R)-diaminocyclohexane-functionalized mesoporous organosilica spheres as chiral stationary phase
文献类型：期刊论文
| 作者 | Zhu, Guiru; Jiang, Dongmei; Yang, Qihua; Yang, Jie; Li, Can |
| 刊名 | journal of chromatography a
 |
| 出版日期 | 2007-05-18 |
| 卷号 | 1149期号:2页码:219-227 |
| 关键词 | bifunctionalized mesoporous organosilica spheres traps-(1R ligand exchange chiral stationary phase HPLC 2R)-diaminocyclohexane |
| 英文摘要 | the bifunctionalized mesoporous organosilica spheres with trans-(1r,2r)-diaminocyclohexane (dach) in the pore were synthesized and their application as chiral stationary phase in high-performance liquid chromatography (hplc) was demonstrated. bifunctionalized mesoporous organosilica spheres with narrow particle size distribution of 5-7 mu m were prepared by the co-condensation of n-[3-(triethoxysilyl)propyl]-trans(1r,2r)-diaminocyclohexane (m(propyl)) with 1,2-bis(trimethoxysilyl)ethane (btme) in basic medium using octadecyltrimethyl ammonium chloride (c(18)tac1) as structural directing agent and ethanol as co-solvent. the morphologies of the bifunctionalized mesoporous organosilicas were sensitive to the molar fraction of m(propyl). at higher m(propyl)/btme molar ratio, the bifunctionalized organosilica spheres with ordered mesoporous structure can be formed in a wide range of synthetic conditions. when the molar percent of m(propyl)/(m(propyl)/btme) is less than 20, the formation of spheres could be hardly observed. the structural order of the materials mainly depends on the base concentration and mpropyi/btme molar ratio in the initial sol mixture. a column packed with the bifunctionalized mesoporous organosilica spheres exhibits higher selectivity and resolution for racemic amino acids than that packed with dach-sio(2) prepared by conventional post-synthesis grafting method. (c) 2007 elsevier b.v. all rights reserved. |
| WOS标题词 | science & technology ; life sciences & biomedicine ; physical sciences |
| 类目[WOS] | biochemical research methods ; chemistry, analytical |
| 研究领域[WOS] | biochemistry & molecular biology ; chemistry |
| 关键词[WOS] | performance liquid-chromatography ; ligand-exchange chromatography ; large-pore ; organic functionality ; silica spheres ; channel walls ; hplc ; separation ; morphology ; surfactant |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000246673000010 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/140418]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhu, Guiru,Jiang, Dongmei,Yang, Qihua,et al. trans-(1R,2R)-diaminocyclohexane-functionalized mesoporous organosilica spheres as chiral stationary phase[J]. journal of chromatography a,2007,1149(2):219-227. |
| APA | Zhu, Guiru,Jiang, Dongmei,Yang, Qihua,Yang, Jie,&Li, Can.(2007).trans-(1R,2R)-diaminocyclohexane-functionalized mesoporous organosilica spheres as chiral stationary phase.journal of chromatography a,1149(2),219-227. |
| MLA | Zhu, Guiru,et al."trans-(1R,2R)-diaminocyclohexane-functionalized mesoporous organosilica spheres as chiral stationary phase".journal of chromatography a 1149.2(2007):219-227. |
入库方式： OAI收割
来源：大连化学物理研究所
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