Molybdenum phosphide, a new hydrazine decomposition catalyst: Microcalorimetry and FTIR studies
文献类型：期刊论文
| 作者 | Cheng, Ruihua; Shu, Yuying; Zheng, Mingyuan; Li, Lin; Sun, Jun; Wang, Xiaodong; Zhang, Tao |
| 刊名 | journal of catalysis
 |
| 出版日期 | 2007-07-25 |
| 卷号 | 249期号:2页码:397-400 |
| 关键词 | hydrazine decomposition molybdenum phosphide molybdenum nitride microcalorimetry FTIR spectroscopy |
| 英文摘要 | unsupported and al2o3-supported molybdenum phosphides (mop) were tested as catalysts for the decomposition of hydrazine (n2h4), in comparison with previously studied mo2n catalysts. the results showed that the activity increased with mop loading on the mop/al2o3 catalysts and that the supported mop catalysts were more stable during hydrazine decomposition compared with the supported mo2n catalysts. ftir results indicated that n2h4 decomposed on the mo sites on the mop, similar to the case of mo2n. ftir and microcalorimetric adsorption measurements showed that nh3 was adsorbed only moderately on the mop catalyst, giving it better catalytic stability than the mo2n, for which strong adsorption of nh3 blocked the active sites and led to a sharp decrease in activity. (c) 2007 elsevier inc. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | chemistry, physical ; engineering, chemical |
| 研究领域[WOS] | chemistry ; engineering |
| 关键词[WOS] | transition-metal phosphides ; nitride catalyst ; iridium catalyst ; carbide ; adsorption |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000248397400028 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/140422]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Cheng, Ruihua,Shu, Yuying,Zheng, Mingyuan,et al. Molybdenum phosphide, a new hydrazine decomposition catalyst: Microcalorimetry and FTIR studies[J]. journal of catalysis,2007,249(2):397-400. |
| APA | Cheng, Ruihua.,Shu, Yuying.,Zheng, Mingyuan.,Li, Lin.,Sun, Jun.,...&Zhang, Tao.(2007).Molybdenum phosphide, a new hydrazine decomposition catalyst: Microcalorimetry and FTIR studies.journal of catalysis,249(2),397-400. |
| MLA | Cheng, Ruihua,et al."Molybdenum phosphide, a new hydrazine decomposition catalyst: Microcalorimetry and FTIR studies".journal of catalysis 249.2(2007):397-400. |
入库方式： OAI收割
来源：大连化学物理研究所
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