Synthesis, crystal structure and thermochemical study of [Gd-2(Gly)(6)(H2O)(4)](ClO4)(6)(H2O)(5)
文献类型：期刊论文
| 作者 | Lu Ji-Lin; Liu Bei-Ping; Tan Zhi-Cheng; Zhang Da-Shun; Li Lin; Chen Yuan-Dao; Shi Quan |
| 刊名 | acta chimica sinica
 |
| 出版日期 | 2007-10-28 |
| 卷号 | 65期号:20页码:2349-2355 |
| 关键词 | gadolinium perchlorate glycine complex crystal structure standard molar enthalpy of formation |
| 英文摘要 | the complex [gd-2(gly)(6)(h2o)(4)](clo4)(6)(h2o)(5) was synthesized by a microwave technology characterized by ir spectra and a tg-dtg technique. the crystal structure of the complex was determined by an x-ray diffraction method. the crystal is a id chain structure, which belongs to a triclinic system with space group p (1) over bar, and cell parameters: a = 1.1569(17) nm, b = 1.4138(2) nm, c = 1.5642(2) nm, alpha = 96.910(2)degrees, beta = 102.735(2)degrees, gamma = 105.512(2)degrees, v = 2.3606(6) nm(3), z = 2, and d-c = 2.144 g.cm(-3). by isoperibol solution-reaction calorimetry, the standard molar enthalpy of formation of the complex was determined to be -(7960.73 +/- 3.23)kj.mol(-1). |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, multidisciplinary |
| 研究领域[WOS] | chemistry |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000250735300025 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/140432]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Hunan Univ Arts & Sci, Dept Chem & Chem Engn, Changde 415000, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Lu Ji-Lin,Liu Bei-Ping,Tan Zhi-Cheng,et al. Synthesis, crystal structure and thermochemical study of [Gd-2(Gly)(6)(H2O)(4)](ClO4)(6)(H2O)(5)[J]. acta chimica sinica,2007,65(20):2349-2355. |
| APA | Lu Ji-Lin.,Liu Bei-Ping.,Tan Zhi-Cheng.,Zhang Da-Shun.,Li Lin.,...&Shi Quan.(2007).Synthesis, crystal structure and thermochemical study of [Gd-2(Gly)(6)(H2O)(4)](ClO4)(6)(H2O)(5).acta chimica sinica,65(20),2349-2355. |
| MLA | Lu Ji-Lin,et al."Synthesis, crystal structure and thermochemical study of [Gd-2(Gly)(6)(H2O)(4)](ClO4)(6)(H2O)(5)".acta chimica sinica 65.20(2007):2349-2355. |
入库方式： OAI收割
来源：大连化学物理研究所
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