Investigation on concentrated V(IV)/V(V) redox reaction by rotating disc voltarnmetry
文献类型：期刊论文
| 作者 | Wen Yue-Hua; Zhang Hua-Min; Qian Peng; Ma Hai-Peng; Yi Bao-Lian; Yang Yu-Sheng |
| 刊名 | chinese journal of chemistry
 |
| 出版日期 | 2007-03-01 |
| 卷号 | 25期号:3页码:278-283 |
| 关键词 | vanadium redox flow battery V(IV)/V(V) couple high concentration rotating-disc electrode parameter |
| 英文摘要 | the kinetic characteristics of the concentrated v(iv)/v(v) couple have been studied at a glassy carbon electrode in sulfuric acid using rotating-disc electrode and cyclic voltammetry. the kinetics of the v(iv)/v(v) redox couple reaction was found to be electrochemically quasi-reversible with the slower kinetics for the v(v) reduction than that for the v(iv) oxidation. and, dependence of diffusion coefficients and kinetic parameters of v(iv) species on the v(iv) and h2so4 concentration was investigated. it is shown that the concentration of active species v(iv) should be over 1 mol(.)l(-1) for the redox flow battery application. further, with increasing the v(iv) and h2so4 concentration, the diffusion coefficients of v(iv) were gradually reduced whereas its kinetics was improved considerably, especially in the case of v(iv) and h2so4 up to 2 and 4 mol(.)l(-1). |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, multidisciplinary |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | flow battery ; cell ; couple |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000244805800004 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/140434]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Full Cell R&D Ctr, Dalian 116023, Peoples R China 2.Res Inst Chem Def, Beijing 100083, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wen Yue-Hua,Zhang Hua-Min,Qian Peng,et al. Investigation on concentrated V(IV)/V(V) redox reaction by rotating disc voltarnmetry[J]. chinese journal of chemistry,2007,25(3):278-283. |
| APA | Wen Yue-Hua,Zhang Hua-Min,Qian Peng,Ma Hai-Peng,Yi Bao-Lian,&Yang Yu-Sheng.(2007).Investigation on concentrated V(IV)/V(V) redox reaction by rotating disc voltarnmetry.chinese journal of chemistry,25(3),278-283. |
| MLA | Wen Yue-Hua,et al."Investigation on concentrated V(IV)/V(V) redox reaction by rotating disc voltarnmetry".chinese journal of chemistry 25.3(2007):278-283. |
入库方式： OAI收割
来源：大连化学物理研究所
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