Use of in situ polymerized phenol-formaldehyde resin to modify a Nafion((R)) membrane for the direct methanol fuel cell
文献类型：期刊论文
| 作者 | Wu, Zhimou; Sun, Gongquan; Jin, Wei; Wang, Qi; Hou, Hongying; Chan, Kwong-Yu; Xin, Qin |
| 刊名 | journal of power sources
 |
| 出版日期 | 2007-05-15 |
| 卷号 | 167期号:2页码:309-314 |
| 关键词 | direct methanol fuel cell methanol crossover Nation((R)) phenol-formaldehyde resin composite membrane |
| 英文摘要 | commercial nafion (r)-115 (trademark registered to dupont) membranes were modified by in situ polymerized phenol formaldehyde resin (pfr) to suppress methanol crossover, and so3- groups were introduced to pfr by post-sulfonatation. a series of membranes with different sulfonated phenol formaldehyde resin (spfr) loadings have been fabricated and investigated. sem-edx characterization shows that the pfr was well dispersed throughout the nafion (r) membrane. the composite membranes have a similar or slightly lower proton conductivity compared with a native nafion (r) membrane, but show a significant reduction in methanol crossover (the methanol permeability of spfr/nafion (r) composite membrane with 2.3 wt.% spfr loading was 1.5 x 10(-6) cm(2) s(-1), compared with the 2.5 x 10(-6) cm(2) s(-1) for the native nafion (r) membrane). in direct methanol fuel cell (dmfc) evaluation, the membrane electrode assembly (mea) using a composite membrane with a 2.3 wt.% spfr loading shows a higher performance than that of a native nafion (r) membrane with 1 m methanol feed, and at higher methanol concentrations (5 m), the composite membrane achieved a 114 mw cm(-2) maximum power density, while the maximum power density of the native nafion (r) was only 78 mw cm(-2). (c) 2007 elsevier b.v. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | electrochemistry ; energy & fuels |
| 研究领域[WOS] | electrochemistry ; energy & fuels |
| 关键词[WOS] | alcohol nanocomposite membranes ; composite membranes ; dmfc ; performance ; permeation ; crossover ; state |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000246542800011 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/140441]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Direct Alcohol Fuel Cells Lab, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China 3.Univ Hong Kong, Dept Chem, Hong Kong, Hong Kong, Peoples R China 4.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wu, Zhimou,Sun, Gongquan,Jin, Wei,et al. Use of in situ polymerized phenol-formaldehyde resin to modify a Nafion((R)) membrane for the direct methanol fuel cell[J]. journal of power sources,2007,167(2):309-314. |
| APA | Wu, Zhimou.,Sun, Gongquan.,Jin, Wei.,Wang, Qi.,Hou, Hongying.,...&Xin, Qin.(2007).Use of in situ polymerized phenol-formaldehyde resin to modify a Nafion((R)) membrane for the direct methanol fuel cell.journal of power sources,167(2),309-314. |
| MLA | Wu, Zhimou,et al."Use of in situ polymerized phenol-formaldehyde resin to modify a Nafion((R)) membrane for the direct methanol fuel cell".journal of power sources 167.2(2007):309-314. |
入库方式： OAI收割
来源：大连化学物理研究所
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