Identification of unknown compounds on the basis of retention index data in comprehensive two-dimensional gas chromatography
文献类型：期刊论文
| 作者 | Pang, Tao; Zhu, Shukui; Lu, Xin; Xu, Guowang |
| 刊名 | journal of separation science
 |
| 出版日期 | 2007-04-01 |
| 卷号 | 30期号:6页码:868-874 |
| 关键词 | alkanes comprehensive two-dimensional gas chromatography isovolatile curve retention index |
| 英文摘要 | the identification of unknown compounds in complex samples is very difficult. comprehensive two-dimensional gas chromatography (gc x gc) provides very good resolution and improved identification reliability. mass spectrometry is a powerful identification tool and retention index data are another good approach to this end. in this study, a second-order polynomial was used to calculate retention index data based on n-alkanes beyond the region of the 'isovolatile' curve in gc x gc, and the results in the 2nd dimension were validated by using the same stationary phase column in one-dimensional gc. to test the usefulness of the method, volatile compounds in a tobacco leaf extract fraction were analyzed using gc x gc, and 60 compounds were identified on the basis of their retention indices. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, analytical |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | flight mass-spectrometry ; tobacco essential oils ; cigarette-smoke ; volatile oil ; polydimethylsiloxane ; hydrocarbons ; fraction ; samples ; system ; food |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000246348000012 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/140443]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, Natl Chromatog R&A Ctr, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Pang, Tao,Zhu, Shukui,Lu, Xin,et al. Identification of unknown compounds on the basis of retention index data in comprehensive two-dimensional gas chromatography[J]. journal of separation science,2007,30(6):868-874. |
| APA | Pang, Tao,Zhu, Shukui,Lu, Xin,&Xu, Guowang.(2007).Identification of unknown compounds on the basis of retention index data in comprehensive two-dimensional gas chromatography.journal of separation science,30(6),868-874. |
| MLA | Pang, Tao,et al."Identification of unknown compounds on the basis of retention index data in comprehensive two-dimensional gas chromatography".journal of separation science 30.6(2007):868-874. |
入库方式： OAI收割
来源：大连化学物理研究所
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