Thermal stability and kinetics of thermal decomposition for protionamide
文献类型:期刊论文
作者 | Wang Shao-Xu; Zhao Zhe; Tan Zhi-Cheng; Li Yan-Sheng; Tong Bo; Shi Quan; Li Ying |
刊名 | acta physico-chimica sinica
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出版日期 | 2007-09-01 |
卷号 | 23期号:9页码:1459-1462 |
关键词 | protionamide kinetics of thermal decomposition thermogravimetry differential thermal analysis thermodynamic property |
英文摘要 | the thermal stability and the kinetics of thermal decomposition of protionamide were studied by thermogravimetry. activation energy e-a of thermal decomposition of this substance was obtained to be 54.65 kj center dot mol(-1) by kissinger method and ozawa-flynn-wall method. kinetics model function and frequency factor a of protionamide were predicted with the malek method, which were f(alpha)=alpha(0.391)(1-alpha)(0.145) and ina=13.12, respectively. moreover, melting point, molar enthalpy and entropy of fusion of this compound were determined to be 414.09 k, 23.21 kj center dot mol(-1), and 56.06 j center dot mol(-1) center dot k-1, respectively. |
WOS标题词 | science & technology ; physical sciences |
类目[WOS] | chemistry, physical |
研究领域[WOS] | chemistry |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000249570000029 |
公开日期 | 2015-11-17 |
源URL | [http://159.226.238.44/handle/321008/140447] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | 1.Dalian Jiaotong Univ, Coll Environm Sci & Chem Engn, Dalian 116028, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Thermochem Lab, Dalian 116023, Liaoning, Peoples R China |
推荐引用方式 GB/T 7714 | Wang Shao-Xu,Zhao Zhe,Tan Zhi-Cheng,et al. Thermal stability and kinetics of thermal decomposition for protionamide[J]. acta physico-chimica sinica,2007,23(9):1459-1462. |
APA | Wang Shao-Xu.,Zhao Zhe.,Tan Zhi-Cheng.,Li Yan-Sheng.,Tong Bo.,...&Li Ying.(2007).Thermal stability and kinetics of thermal decomposition for protionamide.acta physico-chimica sinica,23(9),1459-1462. |
MLA | Wang Shao-Xu,et al."Thermal stability and kinetics of thermal decomposition for protionamide".acta physico-chimica sinica 23.9(2007):1459-1462. |
入库方式: OAI收割
来源:大连化学物理研究所
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