Synthesis, structure and magnetic properties of a new iron phosphonate-oxalate with 3D framework: [Fe(O3PCH3)C2O4)(0.5)(H2O)]
文献类型：期刊论文
| 作者 | Zhang, Yang-Yang; Qi, Yue; Zhang, Ying; Liu, Zi-Yu; Zhao, Yin-Feng; Liu, Zhong-Min |
| 刊名 | materials research bulletin
 |
| 出版日期 | 2007-08-07 |
| 卷号 | 42期号:8页码:1531-1538 |
| 关键词 | A. magnetic materials C. mossbauer spectroscopy D. crystal structure D. magnetic properties |
| 英文摘要 | a new iron phosphonate-oxalate [fe(o3pch3)(c2o4)(0.5)(h2o)] (1), has been synthesized under hydrothermal condition. the single-crystal x-ray diffraction studies reveal that 1 consists of layers of vertex-linked feo6 octahedra and o3pc tetrahedra, which are further connected by bis-chelate oxalate bridges, giving to a 3d structure with 10-membered channels. crystal data: monoclinic, p2(1)/n (no. 14), a = 4.851(2) angstrom, b = 16.803(7) angstrom, c = 7.941(4) angstrom, beta = 107.516(6)degrees, v = 617.2(5) angstrom(3), z = 4, r-1 = 0.0337 and wr(2) = 0.0874 for 1251 reflections [i > 2 sigma(i)]. m6ssbauer spectroscopy measurement confirms the existence of high-spin fe(iii) in 1. magnetic studies show that i exhibits weak ferromagnetism with t-n = 30 k due to a weak spin canting. (c) 2006 elsevier ltd. all rights reserved. |
| WOS标题词 | science & technology ; technology |
| 类目[WOS] | materials science, multidisciplinary |
| 研究领域[WOS] | materials science |
| 关键词[WOS] | single-crystal structure ; hybrid open-framework ; weak ferromagnetism ; diphosphonates ; phosphate ; ligand ; polymer ; unit |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000247786700018 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/140449]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Inst Chem Phys, Appl Catalysis Lab, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Yang-Yang,Qi, Yue,Zhang, Ying,et al. Synthesis, structure and magnetic properties of a new iron phosphonate-oxalate with 3D framework: [Fe(O3PCH3)C2O4)(0.5)(H2O)][J]. materials research bulletin,2007,42(8):1531-1538. |
| APA | Zhang, Yang-Yang,Qi, Yue,Zhang, Ying,Liu, Zi-Yu,Zhao, Yin-Feng,&Liu, Zhong-Min.(2007).Synthesis, structure and magnetic properties of a new iron phosphonate-oxalate with 3D framework: [Fe(O3PCH3)C2O4)(0.5)(H2O)].materials research bulletin,42(8),1531-1538. |
| MLA | Zhang, Yang-Yang,et al."Synthesis, structure and magnetic properties of a new iron phosphonate-oxalate with 3D framework: [Fe(O3PCH3)C2O4)(0.5)(H2O)]".materials research bulletin 42.8(2007):1531-1538. |
入库方式： OAI收割
来源：大连化学物理研究所
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