Ligand and substrate pi-stacking interaction controlled enantioselectivity in the asymmetric aziridination
文献类型：期刊论文
| 作者 | Ma, Linge; Jiao, Peng; Zhang, Qihan; Du, Da-Ming; Xu, Jiaxi |
| 刊名 | tetrahedron-asymmetry
 |
| 出版日期 | 2007-04-30 |
| 卷号 | 18期号:7页码:878-884 |
| 英文摘要 | both the steric hindrance and the electronic effect are important factors for controlling the enantioselectivity in asymmetric catalysis. the substituent-dependent enantioselectivity in the asymmetric aziridination of chalcones catalyzed by 1,8-anthracene-linked bis-oxazoline (anbox) was rationalized to the pi-stacking interaction between the ligand backbone and substrates and primarily confirmed by the use of bulky substrates and catalysts without aromatic backbones. the results provide important information for designing novel ligands and for understanding the influence of the electronic effect in asymmetric catalysis. (c) 2007 elsevier ltd. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, inorganic & nuclear ; chemistry, organic ; chemistry, physical |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | face aromatic interactions ; salen-type-ligands ; molecular recognition ; borane reduction ; chiral ligands ; catalysis ; complex ; olefins ; ketones ; cyclopropanation |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000246878700011 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/140457]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Peking Univ, Coll Chem & Mol Engn, Minist Educ,BNLMS, KEy Lab Bioorgan Chem & Mol Engn, Beijing 100871, Peoples R China |
| 推荐引用方式 GB/T 7714 | Ma, Linge,Jiao, Peng,Zhang, Qihan,et al. Ligand and substrate pi-stacking interaction controlled enantioselectivity in the asymmetric aziridination[J]. tetrahedron-asymmetry,2007,18(7):878-884. |
| APA | Ma, Linge,Jiao, Peng,Zhang, Qihan,Du, Da-Ming,&Xu, Jiaxi.(2007).Ligand and substrate pi-stacking interaction controlled enantioselectivity in the asymmetric aziridination.tetrahedron-asymmetry,18(7),878-884. |
| MLA | Ma, Linge,et al."Ligand and substrate pi-stacking interaction controlled enantioselectivity in the asymmetric aziridination".tetrahedron-asymmetry 18.7(2007):878-884. |
入库方式： OAI收割
来源：大连化学物理研究所
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