1-lithio-1,3-dienes: Useful building blocks for cyclic compounds
文献类型:期刊论文
| 作者 | Xi, Zhenfeng |
| 刊名 | bulletin of the chemical society of japan
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| 出版日期 | 2007-06-15 |
| 卷号 | 80期号:6页码:1021-1032 |
| 英文摘要 | in this account, our recent results on the application of substituted 1-lithio-1,3-dienes as building blocks for the preparation of a wide variety of cyclic compounds and linear compounds are briefly summarized. results have revealed that the essential factor which makes 1-lithio-1,3-diene derivatives useful and unique as building blocks is the intracooperation between the alkenyllithium moiety and the butadienyl skeleton, notwithstanding that the alkenyllithium moiety itself reacts with organic substrates in the usual way. in addition, the substitution patterns and the nature of the substituents on the butadienyl skeleton have been demonstrated to affect remarkably the reaction pathways of 1-lithio-1,3-diene derivatives. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, multidisciplinary |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | multiply substituted cyclopentadienes ; temporary silicon connection ; pi-conjugated systems ; anionic ring-closure ; efficient synthesis ; electrophilic cyclization ; coupling reactions ; 6-substituted phenanthridines ; synthetic applications ; group-14 metalloles |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000248256600001 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/140464] ![]() |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Peking Univ, BNLMS, Key Lab Bioorgan Chem & Mol Engn, Minist Educ,Coll Chem, Beijing 100871, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xi, Zhenfeng. 1-lithio-1,3-dienes: Useful building blocks for cyclic compounds[J]. bulletin of the chemical society of japan,2007,80(6):1021-1032. |
| APA | Xi, Zhenfeng.(2007).1-lithio-1,3-dienes: Useful building blocks for cyclic compounds.bulletin of the chemical society of japan,80(6),1021-1032. |
| MLA | Xi, Zhenfeng."1-lithio-1,3-dienes: Useful building blocks for cyclic compounds".bulletin of the chemical society of japan 80.6(2007):1021-1032. |
入库方式: OAI收割
来源:大连化学物理研究所
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