Thermochemical study on complex of samarium. chloride with glycine, Sm(Gly)(2)Cl-3 center dot 3H(2)O
文献类型:期刊论文
作者 | Lu Ji-Lin; Liu Bei-Ping; Tan Zhi-Cheng; Mang Da-Shun; Chen Yuan-Dao; Li Lin |
刊名 | chinese journal of inorganic chemistry |
出版日期 | 2007-09-01 |
卷号 | 23期号:9页码:1639-1643 |
关键词 | thermochemistry low temperature heat capacity standard enthalpy of formation samarium chloride-glycine complex |
英文摘要 | a complex of samarium with glymine, [sm(gly)(2)cl-3-3h(2)o], was synthesized and characterized by dsc, tg and dtg. a possible mechanism of thermal decomposition of this complex was suggested. the heat capacities of the complex were measured by a precision adiabatic calorimeter over the temperature range from 82 to 375 k. the solution enthalpies of reactants [smcl3.6h(2)o +2gly] and the products [sm (gly)(2)cl-3.3h(2)o +3h(2)o] were determined by an isoperibel solution- reaction calorimeter at 298.15 k, respectively; the standard molar enthalpy of formation of [sm(gly)(2)cl-3.3h(2)o] was calculated through a designed thermochemical cycle. |
WOS标题词 | science & technology ; physical sciences |
类目[WOS] | chemistry, inorganic & nuclear |
研究领域[WOS] | chemistry |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000249881900026 |
公开日期 | 2015-11-17 |
源URL | [http://159.226.238.44/handle/321008/140470] |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | 1.Hunan Univ Arts & Sci, Dept Chem & Chem Engn, Changde 415000, Hunan, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Thermochem Lab, Dalian 116023, Peoples R China |
推荐引用方式 GB/T 7714 | Lu Ji-Lin,Liu Bei-Ping,Tan Zhi-Cheng,et al. Thermochemical study on complex of samarium. chloride with glycine, Sm(Gly)(2)Cl-3 center dot 3H(2)O[J]. chinese journal of inorganic chemistry,2007,23(9):1639-1643. |
APA | Lu Ji-Lin,Liu Bei-Ping,Tan Zhi-Cheng,Mang Da-Shun,Chen Yuan-Dao,&Li Lin.(2007).Thermochemical study on complex of samarium. chloride with glycine, Sm(Gly)(2)Cl-3 center dot 3H(2)O.chinese journal of inorganic chemistry,23(9),1639-1643. |
MLA | Lu Ji-Lin,et al."Thermochemical study on complex of samarium. chloride with glycine, Sm(Gly)(2)Cl-3 center dot 3H(2)O".chinese journal of inorganic chemistry 23.9(2007):1639-1643. |
入库方式: OAI收割
来源:大连化学物理研究所
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