中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Thermochemical study on complex of samarium. chloride with glycine, Sm(Gly)(2)Cl-3 center dot 3H(2)O

文献类型:期刊论文

作者Lu Ji-Lin; Liu Bei-Ping; Tan Zhi-Cheng; Mang Da-Shun; Chen Yuan-Dao; Li Lin
刊名chinese journal of inorganic chemistry
出版日期2007-09-01
卷号23期号:9页码:1639-1643
关键词thermochemistry low temperature heat capacity standard enthalpy of formation samarium chloride-glycine complex
英文摘要a complex of samarium with glymine, [sm(gly)(2)cl-3-3h(2)o], was synthesized and characterized by dsc, tg and dtg. a possible mechanism of thermal decomposition of this complex was suggested. the heat capacities of the complex were measured by a precision adiabatic calorimeter over the temperature range from 82 to 375 k. the solution enthalpies of reactants [smcl3.6h(2)o +2gly] and the products [sm (gly)(2)cl-3.3h(2)o +3h(2)o] were determined by an isoperibel solution- reaction calorimeter at 298.15 k, respectively; the standard molar enthalpy of formation of [sm(gly)(2)cl-3.3h(2)o] was calculated through a designed thermochemical cycle.
WOS标题词science & technology ; physical sciences
类目[WOS]chemistry, inorganic & nuclear
研究领域[WOS]chemistry
收录类别SCI
语种英语
WOS记录号WOS:000249881900026
公开日期2015-11-17
源URL[http://159.226.238.44/handle/321008/140470]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
作者单位1.Hunan Univ Arts & Sci, Dept Chem & Chem Engn, Changde 415000, Hunan, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Thermochem Lab, Dalian 116023, Peoples R China
推荐引用方式
GB/T 7714
Lu Ji-Lin,Liu Bei-Ping,Tan Zhi-Cheng,et al. Thermochemical study on complex of samarium. chloride with glycine, Sm(Gly)(2)Cl-3 center dot 3H(2)O[J]. chinese journal of inorganic chemistry,2007,23(9):1639-1643.
APA Lu Ji-Lin,Liu Bei-Ping,Tan Zhi-Cheng,Mang Da-Shun,Chen Yuan-Dao,&Li Lin.(2007).Thermochemical study on complex of samarium. chloride with glycine, Sm(Gly)(2)Cl-3 center dot 3H(2)O.chinese journal of inorganic chemistry,23(9),1639-1643.
MLA Lu Ji-Lin,et al."Thermochemical study on complex of samarium. chloride with glycine, Sm(Gly)(2)Cl-3 center dot 3H(2)O".chinese journal of inorganic chemistry 23.9(2007):1639-1643.

入库方式: OAI收割

来源:大连化学物理研究所

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