Asymmetric ring-opening of epoxides on chiral Co(Salen) catalyst synthesized in SBA-16 through the "ship in a bottle" strategy
文献类型：期刊论文
| 作者 | Yang, Hengquan; Zhang, Lei; Su, Weiguang; Yang, Qihua; Li, Can |
| 刊名 | journal of catalysis
 |
| 出版日期 | 2007-06-10 |
| 卷号 | 248期号:2页码:204-212 |
| 关键词 | ship in a bottle mesoporous cage-like material salen catalyst asymmetric ring-opening |
| 英文摘要 | chiral co(salen) complex was synthesized in the mesoporous cage of sba-16 through the "ship in a bottle" method. the pore entrance size of sba-16 was precisely tailored by varying the autoclaving time and silylation with phenyltrimethoxysilane to trap co(salen) complex in the cage of sba-16. chiral co(salen) trapped in sba-16 shows enantioselectivity (up to 87-96% ee) as high as that of the homogeneous catalyst for the asymmetric ring opening of terminal epoxides and can be recycled at least 10 times with no apparent loss of activity. the activity for the catalyst trapped inside sba-16 can be significantly increased when the surface is modified with organic groups. this work extends the "ship in a bottle" synthesis from microporous materials to mesoporous cage-like materials and develops an effective strategy to trap metal complex catalyst with large molecular size into the nanopores or cavities of mesoporous materials. (c) 2007 elsevier inc. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | chemistry, physical ; engineering, chemical |
| 研究领域[WOS] | chemistry ; engineering |
| 关键词[WOS] | heterogeneous enantioselective catalyst ; hydrolytic kinetic resolution ; mesoporous silica ; salen complexes ; zeolite-y ; terminal epoxides ; epoxidation ; oxidation ; mcm-41 ; temperature |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000247327300006 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/140473]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yang, Hengquan,Zhang, Lei,Su, Weiguang,et al. Asymmetric ring-opening of epoxides on chiral Co(Salen) catalyst synthesized in SBA-16 through the "ship in a bottle" strategy[J]. journal of catalysis,2007,248(2):204-212. |
| APA | Yang, Hengquan,Zhang, Lei,Su, Weiguang,Yang, Qihua,&Li, Can.(2007).Asymmetric ring-opening of epoxides on chiral Co(Salen) catalyst synthesized in SBA-16 through the "ship in a bottle" strategy.journal of catalysis,248(2),204-212. |
| MLA | Yang, Hengquan,et al."Asymmetric ring-opening of epoxides on chiral Co(Salen) catalyst synthesized in SBA-16 through the "ship in a bottle" strategy".journal of catalysis 248.2(2007):204-212. |
入库方式： OAI收割
来源：大连化学物理研究所
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