Thermal decomposition of Mo(CO)(6) on thin Al2O3 film: A combinatorial investigation by XPS and UPS
文献类型：期刊论文
| 作者 | Jiang, Zhiquan; Huang, Weixin; Zhang, Zhen; Zhao, Hong; Tan, Dali; Bao, Xinhe |
| 刊名 | surface science
 |
| 出版日期 | 2007-02-01 |
| 卷号 | 601期号:3页码:844-851 |
| 关键词 | molybdenum hexacarbonyl thin Al2O3 film thermal decomposition X-ray photoelectron spectroscopy ultraviolet photoelectron spectroscopy |
| 英文摘要 | a thin and homogeneous alumina film was prepared by deposition and oxidation of aluminum on a refractory re(0001) substrate under ultrahigh vacuum conditions. x-ray photoelectron spectroscopy (xps), ultraviolet photoelectron spectroscopy (ups) and high-resolution electron-energy-loss spectroscopy (hreels) demonstrate that the oxide film is long-range ordered, essentially stoichiometric and free from surface hydroxyl groups. the chemisorption and thermal decomposition of mo(co)(6) on the al2o3 film were investigated by means of xps and ups. mo(co)(6) adsorbs molecularly on the oxide film at 100 k; however, thermal decomposition of the adsorbate occurs upon annealing at high temperatures. consequently the metallic molybdenum clusters are deposited on the thin alumina film via complete decarbonylation of mo(co)(6). (c) 2006 elsevier b.v. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, physical ; physics, condensed matter |
| 研究领域[WOS] | chemistry ; physics |
| 关键词[WOS] | hot-electron attachment ; aluminum-oxide films ; molybdenum hexacarbonyl ; high-temperatures ; supported molybdenum ; surface-chemistry ; force constants ; direct photoexcitation ; photoelectron-spectra ; metal hexacarbonyls |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000244372900036 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/140478]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 2.Univ Sci & Technol China, Dept Chem Phys, Hefei 230026, Peoples R China |
| 推荐引用方式 GB/T 7714 | Jiang, Zhiquan,Huang, Weixin,Zhang, Zhen,et al. Thermal decomposition of Mo(CO)(6) on thin Al2O3 film: A combinatorial investigation by XPS and UPS[J]. surface science,2007,601(3):844-851. |
| APA | Jiang, Zhiquan,Huang, Weixin,Zhang, Zhen,Zhao, Hong,Tan, Dali,&Bao, Xinhe.(2007).Thermal decomposition of Mo(CO)(6) on thin Al2O3 film: A combinatorial investigation by XPS and UPS.surface science,601(3),844-851. |
| MLA | Jiang, Zhiquan,et al."Thermal decomposition of Mo(CO)(6) on thin Al2O3 film: A combinatorial investigation by XPS and UPS".surface science 601.3(2007):844-851. |
入库方式： OAI收割
来源：大连化学物理研究所
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