Microencapsulation of n-eicosane as energy storage material synthesized by interfacial polymerization
文献类型:期刊论文
作者 | Lan Xiao-Zheng; Yang Chang-Guang; Tan Zhi-Cheng; Sun Li-Xian; Xu Fen |
刊名 | acta physico-chimica sinica
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出版日期 | 2007-04-01 |
卷号 | 23期号:4页码:581-584 |
关键词 | phase change material n-eicosane microcapsule interfacial polymerization |
英文摘要 | for heat energy storage application, polyurea microcapsules containing phase change material, n-eicosane, were synthesized by interfacial polymerization method with toluene -2,4-diisocyanate (tdi) and ethylene diamine (eda) as monomers in an emulsion system. poly (ethylene glycol) octyl-phenyl ether (op), a nonionic surfactant, was the emulsifier for the system. the experiments indicated that tdi was reacted with eda in a mass ratio of 1.9 to 1. the sizes of microcapsules were analyzed with tem and laser particle analyzer, which showed the empty microcapsules were about 0.2 mu m and those containing n-eicosane were 2-6 mu m. ftir spectra proved the formation of wall material, polyurea, from the two monomers, tdi and eda. encapsulation efficiency of n-eicosane was about 75%. microcapsules of n-eicosane melted at a temperature close to that of n-eicosane, while its stored heat energy varied with the amount of core material n-eicosane. thermogravimetric analysis revealed that the core material n-eicosane, micro-n-eicosane, and wall material polyurea could withstand temperatures up to 130 degrees c, 170 degrees c, and 270 degrees c, respectively. |
WOS标题词 | science & technology ; physical sciences |
类目[WOS] | chemistry, physical |
研究领域[WOS] | chemistry |
关键词[WOS] | phase-change material ; polyurea ; system |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000245883400025 |
公开日期 | 2015-11-17 |
源URL | [http://159.226.238.44/handle/321008/140480] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Thermochem Lab, Dalian 116023, Peoples R China 2.Shandong Agr Univ, Coll Chem & Mat Sci, Tai An 271018, Shandong Provin, Peoples R China |
推荐引用方式 GB/T 7714 | Lan Xiao-Zheng,Yang Chang-Guang,Tan Zhi-Cheng,et al. Microencapsulation of n-eicosane as energy storage material synthesized by interfacial polymerization[J]. acta physico-chimica sinica,2007,23(4):581-584. |
APA | Lan Xiao-Zheng,Yang Chang-Guang,Tan Zhi-Cheng,Sun Li-Xian,&Xu Fen.(2007).Microencapsulation of n-eicosane as energy storage material synthesized by interfacial polymerization.acta physico-chimica sinica,23(4),581-584. |
MLA | Lan Xiao-Zheng,et al."Microencapsulation of n-eicosane as energy storage material synthesized by interfacial polymerization".acta physico-chimica sinica 23.4(2007):581-584. |
入库方式: OAI收割
来源:大连化学物理研究所
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