中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Microencapsulation of n-eicosane as energy storage material synthesized by interfacial polymerization

文献类型:期刊论文

作者Lan Xiao-Zheng; Yang Chang-Guang; Tan Zhi-Cheng; Sun Li-Xian; Xu Fen
刊名acta physico-chimica sinica
出版日期2007-04-01
卷号23期号:4页码:581-584
关键词phase change material n-eicosane microcapsule interfacial polymerization
英文摘要for heat energy storage application, polyurea microcapsules containing phase change material, n-eicosane, were synthesized by interfacial polymerization method with toluene -2,4-diisocyanate (tdi) and ethylene diamine (eda) as monomers in an emulsion system. poly (ethylene glycol) octyl-phenyl ether (op), a nonionic surfactant, was the emulsifier for the system. the experiments indicated that tdi was reacted with eda in a mass ratio of 1.9 to 1. the sizes of microcapsules were analyzed with tem and laser particle analyzer, which showed the empty microcapsules were about 0.2 mu m and those containing n-eicosane were 2-6 mu m. ftir spectra proved the formation of wall material, polyurea, from the two monomers, tdi and eda. encapsulation efficiency of n-eicosane was about 75%. microcapsules of n-eicosane melted at a temperature close to that of n-eicosane, while its stored heat energy varied with the amount of core material n-eicosane. thermogravimetric analysis revealed that the core material n-eicosane, micro-n-eicosane, and wall material polyurea could withstand temperatures up to 130 degrees c, 170 degrees c, and 270 degrees c, respectively.
WOS标题词science & technology ; physical sciences
类目[WOS]chemistry, physical
研究领域[WOS]chemistry
关键词[WOS]phase-change material ; polyurea ; system
收录类别SCI
语种英语
WOS记录号WOS:000245883400025
公开日期2015-11-17
源URL[http://159.226.238.44/handle/321008/140480]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, Thermochem Lab, Dalian 116023, Peoples R China
2.Shandong Agr Univ, Coll Chem & Mat Sci, Tai An 271018, Shandong Provin, Peoples R China
推荐引用方式
GB/T 7714
Lan Xiao-Zheng,Yang Chang-Guang,Tan Zhi-Cheng,et al. Microencapsulation of n-eicosane as energy storage material synthesized by interfacial polymerization[J]. acta physico-chimica sinica,2007,23(4):581-584.
APA Lan Xiao-Zheng,Yang Chang-Guang,Tan Zhi-Cheng,Sun Li-Xian,&Xu Fen.(2007).Microencapsulation of n-eicosane as energy storage material synthesized by interfacial polymerization.acta physico-chimica sinica,23(4),581-584.
MLA Lan Xiao-Zheng,et al."Microencapsulation of n-eicosane as energy storage material synthesized by interfacial polymerization".acta physico-chimica sinica 23.4(2007):581-584.

入库方式: OAI收割

来源:大连化学物理研究所

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