Dynamical resonance in F+H-2 chemical reaction and rotational excitation effect
文献类型:期刊论文
作者 | Yang XueMing; Xie DaiQian; Zhang DongHui |
刊名 | chinese science bulletin
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出版日期 | 2007-04-01 |
卷号 | 52期号:8页码:1009-1012 |
关键词 | Feshbach resonance reaction resonance state-to-state reactive scattering reaction dynamics quantum interference |
英文摘要 | reaction resonance is a frontier topic in chemical dynamics research, and it is also essential to the understanding of mechanisms of elementary chemical reactions. this short, article describes an important development in the frontier of research. experimental evidence of reaction resonance has been detected in a full quantum state resolved reactive scattering study of the f+h-2 reaction. highly accurate full quantum scattering theoretical modeling shows that the reaction resonance is caused by two feshbach resonance states. further studies show that quantum interference is present between the two resonance states for the forward scattering product. this study is a significant step forward in our understanding of chemical reaction resonance in the benchmark f+h-2 system. further experimental studies on the effect of h-2 rotational excitation on dynamical resonance have been carried out. dynamical resonance in the f+h-2 j = 1) reaction has also been observed. |
WOS标题词 | science & technology |
类目[WOS] | multidisciplinary sciences |
研究领域[WOS] | science & technology - other topics |
关键词[WOS] | potential-energy surface ; quantum ; scattering |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000247163200001 |
公开日期 | 2015-11-17 |
源URL | [http://159.226.238.44/handle/321008/140512] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China 2.Nanjing Univ, Inst Theoret & Computat Chem, Coll Chem & Chem Engn, Nanjing 210093, Peoples R China |
推荐引用方式 GB/T 7714 | Yang XueMing,Xie DaiQian,Zhang DongHui. Dynamical resonance in F+H-2 chemical reaction and rotational excitation effect[J]. chinese science bulletin,2007,52(8):1009-1012. |
APA | Yang XueMing,Xie DaiQian,&Zhang DongHui.(2007).Dynamical resonance in F+H-2 chemical reaction and rotational excitation effect.chinese science bulletin,52(8),1009-1012. |
MLA | Yang XueMing,et al."Dynamical resonance in F+H-2 chemical reaction and rotational excitation effect".chinese science bulletin 52.8(2007):1009-1012. |
入库方式: OAI收割
来源:大连化学物理研究所
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