Experimental study of C2Cl3+NO2 reaction
文献类型：期刊论文
| 作者 | Xiang, Tian-Cheng; Liu, Kun-Hui; Su, Hong-Nnei |
| 刊名 | chinese journal of chemical physics
 |
| 出版日期 | 2007-08-27 |
| 卷号 | 20期号:4页码:407-411 |
| 关键词 | TR-FTIR C2Cl3 vibrational population reaction mechanism |
| 英文摘要 | the free radical reaction of c2cl3 with no2 was investigated by step-scan time-resolved ftir (tr-ftir) emission spectroscopy. due to the vibrationally excited products of cl2co, no, and co, strong ir emission bands were observed with high resolution tr-ftir spectra. four reaction channels forming c2cl3o+no, ccl3co+no, co+no+ccl3, and clcno+cl2co were elucidated, respectively. spectral fitting showed that the product co was highly vibrationally excited with the nascent average vibrational energy of 60.2 kj/mol. possible reaction mechanism via intermediates c2cl3no2 and c2cl3ono was proposed. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | physics, atomic, molecular & chemical |
| 研究领域[WOS] | physics |
| 关键词[WOS] | molecular-oxygen ; rate constants ; hydrocarbon radicals ; vinyl radicals ; ftir emission ; ab-initio ; kinetics ; no2 ; c2h3 ; chlorine |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000249465100013 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/140541]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, State Key Lab Mol React Dynam, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xiang, Tian-Cheng,Liu, Kun-Hui,Su, Hong-Nnei. Experimental study of C2Cl3+NO2 reaction[J]. chinese journal of chemical physics,2007,20(4):407-411. |
| APA | Xiang, Tian-Cheng,Liu, Kun-Hui,&Su, Hong-Nnei.(2007).Experimental study of C2Cl3+NO2 reaction.chinese journal of chemical physics,20(4),407-411. |
| MLA | Xiang, Tian-Cheng,et al."Experimental study of C2Cl3+NO2 reaction".chinese journal of chemical physics 20.4(2007):407-411. |
入库方式： OAI收割
来源：大连化学物理研究所
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