Synthesis of a binuclear copper(II) compound a copper source for preparation of environmental catalyst
文献类型:期刊论文
作者 | Tang, Xingfu; Liang, Fupei; Chen, Junh; Li, Yonggang; Xu, Yide; Shen, Wenjie |
刊名 | materials chemistry and physics
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出版日期 | 2007-12-15 |
卷号 | 106期号:2-3页码:159-163 |
关键词 | copper precursor organometallic compound thermal analysis high dispersion complete oxidation of formaldehyde |
英文摘要 | binuclear copper(ii) compound [cu-2(nta)(phen)(3)]no3 center dot 6h(2)o was synthesized (nta=nitrilotriacetate, phen=1,10-phenanthroline), and characterized by single crystal x-ray diffraction and thermal gravimetric analyses. this compound used as a copper source was decomposed on mnox-ceo2 in n-2 at 400 degrees c and subsequently in air at 500 degrees c to obtain a cu/mnox-ceo2 catalyst. the results of catalytic activity test showed that compared with a referential cu/mnox-ceo2 catalyst prepared using conventional copper nitrate as a precursor, the obtained cu/mnox-ceo2 catalyst exhibited higher catalytic activity toward complete oxidation of formaldehyde. analyses by bet and xrd techniques revealed that cuo with smaller particle sizes was highly dispersed on the external surface of the mnox-ceo2 mixed oxide, which was responsible for its higher catalytic activity. (c) 2007 elsevier b.v. all rights reserved. |
WOS标题词 | science & technology ; technology |
类目[WOS] | materials science, multidisciplinary |
研究领域[WOS] | materials science |
关键词[WOS] | complete oxidation ; crystal-structures ; mesoporous silica ; oxide catalysts ; precursor ; acid ; formaldehyde ; temperature ; deposition ; complexes |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000251202900001 |
公开日期 | 2015-11-17 |
源URL | [http://159.226.238.44/handle/321008/140550] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | 1.Guangxi Normal Univ, Sch Chem & Chem Engn, Guilin 541004, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalyst, Dalian 116023, Peoples R China |
推荐引用方式 GB/T 7714 | Tang, Xingfu,Liang, Fupei,Chen, Junh,et al. Synthesis of a binuclear copper(II) compound a copper source for preparation of environmental catalyst[J]. materials chemistry and physics,2007,106(2-3):159-163. |
APA | Tang, Xingfu,Liang, Fupei,Chen, Junh,Li, Yonggang,Xu, Yide,&Shen, Wenjie.(2007).Synthesis of a binuclear copper(II) compound a copper source for preparation of environmental catalyst.materials chemistry and physics,106(2-3),159-163. |
MLA | Tang, Xingfu,et al."Synthesis of a binuclear copper(II) compound a copper source for preparation of environmental catalyst".materials chemistry and physics 106.2-3(2007):159-163. |
入库方式: OAI收割
来源:大连化学物理研究所
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