中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Synthesis of a binuclear copper(II) compound a copper source for preparation of environmental catalyst

文献类型:期刊论文

作者Tang, Xingfu; Liang, Fupei; Chen, Junh; Li, Yonggang; Xu, Yide; Shen, Wenjie
刊名materials chemistry and physics
出版日期2007-12-15
卷号106期号:2-3页码:159-163
关键词copper precursor organometallic compound thermal analysis high dispersion complete oxidation of formaldehyde
英文摘要binuclear copper(ii) compound [cu-2(nta)(phen)(3)]no3 center dot 6h(2)o was synthesized (nta=nitrilotriacetate, phen=1,10-phenanthroline), and characterized by single crystal x-ray diffraction and thermal gravimetric analyses. this compound used as a copper source was decomposed on mnox-ceo2 in n-2 at 400 degrees c and subsequently in air at 500 degrees c to obtain a cu/mnox-ceo2 catalyst. the results of catalytic activity test showed that compared with a referential cu/mnox-ceo2 catalyst prepared using conventional copper nitrate as a precursor, the obtained cu/mnox-ceo2 catalyst exhibited higher catalytic activity toward complete oxidation of formaldehyde. analyses by bet and xrd techniques revealed that cuo with smaller particle sizes was highly dispersed on the external surface of the mnox-ceo2 mixed oxide, which was responsible for its higher catalytic activity. (c) 2007 elsevier b.v. all rights reserved.
WOS标题词science & technology ; technology
类目[WOS]materials science, multidisciplinary
研究领域[WOS]materials science
关键词[WOS]complete oxidation ; crystal-structures ; mesoporous silica ; oxide catalysts ; precursor ; acid ; formaldehyde ; temperature ; deposition ; complexes
收录类别SCI
语种英语
WOS记录号WOS:000251202900001
公开日期2015-11-17
源URL[http://159.226.238.44/handle/321008/140550]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
作者单位1.Guangxi Normal Univ, Sch Chem & Chem Engn, Guilin 541004, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalyst, Dalian 116023, Peoples R China
推荐引用方式
GB/T 7714
Tang, Xingfu,Liang, Fupei,Chen, Junh,et al. Synthesis of a binuclear copper(II) compound a copper source for preparation of environmental catalyst[J]. materials chemistry and physics,2007,106(2-3):159-163.
APA Tang, Xingfu,Liang, Fupei,Chen, Junh,Li, Yonggang,Xu, Yide,&Shen, Wenjie.(2007).Synthesis of a binuclear copper(II) compound a copper source for preparation of environmental catalyst.materials chemistry and physics,106(2-3),159-163.
MLA Tang, Xingfu,et al."Synthesis of a binuclear copper(II) compound a copper source for preparation of environmental catalyst".materials chemistry and physics 106.2-3(2007):159-163.

入库方式: OAI收割

来源:大连化学物理研究所

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