The electrochemical properties of AB(3)/polyaniline composites
文献类型：期刊论文
| 作者 | Qi, Yan-Ni1,2; Xu, Fen1; Chu, Hai-Liang1,2; Sun, Li-Xian1,3; Jiang, T.1; Zhu, M.4 |
| 刊名 | international journal of hydrogen energy
 |
| 出版日期 | 2007-12-01 |
| 卷号 | 32期号:18页码:4894-4899 |
| 关键词 | AB(3)/PANI composite electrochemical properties discharge cycle stability |
| 英文摘要 | the la(0.7)mg(0.25)ti(0.05)ni(2.975)co(0.525) (ab(3)) alloy was modified with different contents of polyaniline (pani) through ball milling. xrd, sem and ftir were used to characterize the properties of the ab(3)/x pant composites (x=1, 2, 3 and 4wt%). the effects of pani on the electrochemical properties of ab(3) alloy electrode were studied by charge-discharge, electrochemical impedance spectroscopy (eis), linear polarization (lp) and potentiostatic discharge experiments. the xrd, sem and ftir results showed that ball milling did not change the characterizations of pant and ab(3) alloy but decreased the average particle size of ab(3) alloy. the charge-discharge results indicated that the maximum discharge capacity of ab(3) alloy electrode decreased with the addition of pant. however, the discharge cycle stability of ab(3)/pani composite electrodes increased firstly and then decreased with the increase in pant content. the eis and lp curves showed the same trends with the discharge cycle stability. the hydrogen diffusion coefficients of ab(3)/pani composites were estimated from the potentiostatic discharge curves, indicated the opposite trend with the discharge cycle stability. when the pant content was equal to 3 wt%, the ab(3)/pani composite electrode exhibited an optimal electrochemical kinetic property. (c) 2007 international association for hydrogen energy. published by elsevier ltd. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | chemistry, physical ; electrochemistry ; energy & fuels |
| 研究领域[WOS] | chemistry ; electrochemistry ; energy & fuels |
| 关键词[WOS] | hydrogen storage alloys ; metal hydride electrodes ; ni ; substitution ; batteries ; behavior ; polymer ; pd |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000252259500032 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/140551]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Mat Thermochem Lab, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Educ Sch Chinese Acad Sci, Beijing 100049, Peoples R China 3.Jinan Univ, Dept Chem, Guangzhou 510632, Peoples R China 4.S China Univ Technol, Sch Mech Engn, Guangzhou 510641, Peoples R China |
| 推荐引用方式 GB/T 7714 | Qi, Yan-Ni,Xu, Fen,Chu, Hai-Liang,et al. The electrochemical properties of AB(3)/polyaniline composites[J]. international journal of hydrogen energy,2007,32(18):4894-4899. |
| APA | Qi, Yan-Ni,Xu, Fen,Chu, Hai-Liang,Sun, Li-Xian,Jiang, T.,&Zhu, M..(2007).The electrochemical properties of AB(3)/polyaniline composites.international journal of hydrogen energy,32(18),4894-4899. |
| MLA | Qi, Yan-Ni,et al."The electrochemical properties of AB(3)/polyaniline composites".international journal of hydrogen energy 32.18(2007):4894-4899. |
入库方式： OAI收割
来源：大连化学物理研究所
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