Syntheses of La1-xBaxMn2Al10O19 catalysts (x=0, 0.05) in a novel microemulsion of water/2-propanol/1-butanol and their high activities in methane combustion
文献类型：期刊论文
| 作者 | Teng, Fei; Liang, Shuhui; Gauge, Buergen; Zhu, Yongfa; Xu, Jinguang; Wen, Guodong; Tian, Zhijian; Wang, Zheming; Yang, Xiaomei; Xiong, Guoxing |
| 刊名 | journal of physical chemistry c
 |
| 出版日期 | 2007-07-26 |
| 卷号 | 111期号:29页码:10941-10947 |
| 英文摘要 | in this work, a novel system of water/2-propanol/1-butanol (w/ip/nb) was developed to synthesize la1-xbaxmn2al10o19 (x = 0, 0.05) catalysts. these catalysts were also synthesized by the hydrolysis of the alkoxides in distilled water. the physicochemical properties of the catalysts were characterized by transmission electron microscopy, x-ray powder diffraction, and n-2 adsorption isotherm measurements. the effects of the reaction medium and drying method on the properties of the catalysts were investigated. the results showed that la0.95ba0.05mn2al10o19 catalyst synthesized in w/ip/nb had a higher activity in methane combustion (t-10% = 425 degrees c; t-10% = the temperature at 10% methane conversion) than that prepared in distilled water (t-10% = 515 degrees c). after the reaction was run at 700 degrees c for 100 h under the reaction conditions, la0.95ba0.05mn2al10o19 catalyst synthesized in w/ip/nb showed a higher stability than that prepared in distilled water. the lamn2al10o19 synthesized by subcritical drying showed a higher activity (t-10% = 440 degrees c) than that prepared by conventional oven drying. la0.95ba0.05mn2al10o19 catalyst showed a higher activity than lamn2al10o19, which was ascribed to the partial substitution of ba for la. furthermore, the structure property of water in w/ip/nb was investigated by means of ft-ir, nmr, electric conductivity, and laser light scattering granulometry. it was proposed that a novel reverse microemulsion of w/ip/nb is formed by distilled water, 2-propanol, and 1-butanol. the hydrolysis of the alkoxides in w/ip/nb was controlled efficiently, just as in a conventional reverse microemulsion. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | chemistry, physical ; nanoscience & nanotechnology ; materials science, multidisciplinary |
| 研究领域[WOS] | chemistry ; science & technology - other topics ; materials science |
| 关键词[WOS] | self-association ; aqueous-solution ; water mixtures ; phase-behavior ; surface-area ; systems ; temperature ; bao.6al2o3 ; diffusion ; oxidation |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000248121600028 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/140553]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Tsing Hua Univ, Dept Chem, Beijing 100084, Peoples R China 2.Yantai Univ, Inst Appl Catalysis, Yantai 264005, Peoples R China 3.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Teng, Fei,Liang, Shuhui,Gauge, Buergen,et al. Syntheses of La1-xBaxMn2Al10O19 catalysts (x=0, 0.05) in a novel microemulsion of water/2-propanol/1-butanol and their high activities in methane combustion[J]. journal of physical chemistry c,2007,111(29):10941-10947. |
| APA | Teng, Fei.,Liang, Shuhui.,Gauge, Buergen.,Zhu, Yongfa.,Xu, Jinguang.,...&Xiong, Guoxing.(2007).Syntheses of La1-xBaxMn2Al10O19 catalysts (x=0, 0.05) in a novel microemulsion of water/2-propanol/1-butanol and their high activities in methane combustion.journal of physical chemistry c,111(29),10941-10947. |
| MLA | Teng, Fei,et al."Syntheses of La1-xBaxMn2Al10O19 catalysts (x=0, 0.05) in a novel microemulsion of water/2-propanol/1-butanol and their high activities in methane combustion".journal of physical chemistry c 111.29(2007):10941-10947. |
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来源：大连化学物理研究所
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