中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Catalytic behavior of hydrothermally synthesized La0.5Sr0.5MnO3 single-crystal cubes in the oxidation of CO and CH4

文献类型:期刊论文

作者Teng, Fei; Han, Wei; Liang, Shuhui; Gaugeu, Buergen; Zong, Ruilong; Zhu, Yongfa
刊名journal of catalysis
出版日期2007-08-15
卷号250期号:1页码:1-11
关键词La0.5Sr0.5MnO3 single crystals cubes hydrothermal catalytic oxidation CO CH4 thermal stability
英文摘要la0.5sr0.5mno3 single-crystal cubes and nanoparticles were synthesized by hydrothermal and citrate routes, respectively. their catalytic properties for low-temperature co oxidation and high-temperature ch4 combustion were evaluated, and the effects of crystal structure and morphology on the catalytic properties of the catalysts were investigated. the activity (220 degrees c of the complete oxidation of co over the single cubes was lower than that (190 degrees c over the nanoparticles. after running at 600 degrees c for 48 h under the reaction conditions, the surface area of the nanoparticles decreased significantly, but the cubes nearly maintained their surface area. for ch4 combustion, the la0.5sr0.5mno3 cubes showed a higher activity (t-10 = 360 degrees c, t-10: the temperature at 10% conversion of ch4) than the nanoparticles (t-10 = 440 degrees c. the different activities were attributed to their different crystal structures and morphologies. (c) 2007 elsevier inc. all rights reserved.
WOS标题词science & technology ; physical sciences ; technology
类目[WOS]chemistry, physical ; engineering, chemical
研究领域[WOS]chemistry ; engineering
关键词[WOS]carbon-monoxide oxidation ; perovskite-type oxides ; raman-scattering ; lanthanum manganite ; magnetic-properties ; low-temperature ; combustion ; transition ; nanowires ; strontium
收录类别SCI
语种英语
WOS记录号WOS:000249104000001
公开日期2015-11-17
源URL[http://159.226.238.44/handle/321008/140563]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
作者单位1.Tsing Hua Univ, Dept Chem, Beijing 100084, Peoples R China
2.Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
推荐引用方式
GB/T 7714
Teng, Fei,Han, Wei,Liang, Shuhui,et al. Catalytic behavior of hydrothermally synthesized La0.5Sr0.5MnO3 single-crystal cubes in the oxidation of CO and CH4[J]. journal of catalysis,2007,250(1):1-11.
APA Teng, Fei,Han, Wei,Liang, Shuhui,Gaugeu, Buergen,Zong, Ruilong,&Zhu, Yongfa.(2007).Catalytic behavior of hydrothermally synthesized La0.5Sr0.5MnO3 single-crystal cubes in the oxidation of CO and CH4.journal of catalysis,250(1),1-11.
MLA Teng, Fei,et al."Catalytic behavior of hydrothermally synthesized La0.5Sr0.5MnO3 single-crystal cubes in the oxidation of CO and CH4".journal of catalysis 250.1(2007):1-11.

入库方式: OAI收割

来源:大连化学物理研究所

浏览0
下载0
收藏0
其他版本

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。