Catalytic behavior of hydrothermally synthesized La0.5Sr0.5MnO3 single-crystal cubes in the oxidation of CO and CH4
文献类型:期刊论文
作者 | Teng, Fei; Han, Wei; Liang, Shuhui; Gaugeu, Buergen; Zong, Ruilong; Zhu, Yongfa |
刊名 | journal of catalysis
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出版日期 | 2007-08-15 |
卷号 | 250期号:1页码:1-11 |
关键词 | La0.5Sr0.5MnO3 single crystals cubes hydrothermal catalytic oxidation CO CH4 thermal stability |
英文摘要 | la0.5sr0.5mno3 single-crystal cubes and nanoparticles were synthesized by hydrothermal and citrate routes, respectively. their catalytic properties for low-temperature co oxidation and high-temperature ch4 combustion were evaluated, and the effects of crystal structure and morphology on the catalytic properties of the catalysts were investigated. the activity (220 degrees c of the complete oxidation of co over the single cubes was lower than that (190 degrees c over the nanoparticles. after running at 600 degrees c for 48 h under the reaction conditions, the surface area of the nanoparticles decreased significantly, but the cubes nearly maintained their surface area. for ch4 combustion, the la0.5sr0.5mno3 cubes showed a higher activity (t-10 = 360 degrees c, t-10: the temperature at 10% conversion of ch4) than the nanoparticles (t-10 = 440 degrees c. the different activities were attributed to their different crystal structures and morphologies. (c) 2007 elsevier inc. all rights reserved. |
WOS标题词 | science & technology ; physical sciences ; technology |
类目[WOS] | chemistry, physical ; engineering, chemical |
研究领域[WOS] | chemistry ; engineering |
关键词[WOS] | carbon-monoxide oxidation ; perovskite-type oxides ; raman-scattering ; lanthanum manganite ; magnetic-properties ; low-temperature ; combustion ; transition ; nanowires ; strontium |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000249104000001 |
公开日期 | 2015-11-17 |
源URL | [http://159.226.238.44/handle/321008/140563] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | 1.Tsing Hua Univ, Dept Chem, Beijing 100084, Peoples R China 2.Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China |
推荐引用方式 GB/T 7714 | Teng, Fei,Han, Wei,Liang, Shuhui,et al. Catalytic behavior of hydrothermally synthesized La0.5Sr0.5MnO3 single-crystal cubes in the oxidation of CO and CH4[J]. journal of catalysis,2007,250(1):1-11. |
APA | Teng, Fei,Han, Wei,Liang, Shuhui,Gaugeu, Buergen,Zong, Ruilong,&Zhu, Yongfa.(2007).Catalytic behavior of hydrothermally synthesized La0.5Sr0.5MnO3 single-crystal cubes in the oxidation of CO and CH4.journal of catalysis,250(1),1-11. |
MLA | Teng, Fei,et al."Catalytic behavior of hydrothermally synthesized La0.5Sr0.5MnO3 single-crystal cubes in the oxidation of CO and CH4".journal of catalysis 250.1(2007):1-11. |
入库方式: OAI收割
来源:大连化学物理研究所
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