Epoxidation of cyclohexene catalyzed by the vanadium bromoperoxidase from Corallina officinalis
文献类型：期刊论文
| 作者 | Yu Yao; Jin Yan; Wu Peichun; Zhang Wei |
| 刊名 | chinese journal of catalysis
 |
| 出版日期 | 2007-10-01 |
| 卷号 | 28期号:10页码:915-918 |
| 关键词 | bromoperoxidase cyclohexene epoxidation epoxy cyclohexane |
| 英文摘要 | the epoxidation of cyclohexene catalyzed by a vanadium bromoperoxidase from the red algae corallina officinalis has been investigated. the reaction was performed in a water-organic solvent biphasic system. the effects of oxidants and their loading method, ph, temperature, and the concentration of vanadium bromoperoxidase and kbr on the epoxidation were studied. the optimal conditions were as follows: the reaction temperature was 55 degrees c, and 50 mu l of 2.29 mol/l h2o2 was added every 10 min to the tris-hcl buffer at ph 6.0 containing 50 mmol/l of kbr and 32 u/ml of the enzyme (final concentration). under these conditions, the maximum epoxy cyclohexane yield and selectivity were 41. 5 % and 82. 2 %, respectively. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | chemistry, applied ; chemistry, physical ; engineering, chemical |
| 研究领域[WOS] | chemistry ; engineering |
| 关键词[WOS] | haloperoxidases ; biocatalysts |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000250972600016 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/140575]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Grad Univ Beijing, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yu Yao,Jin Yan,Wu Peichun,et al. Epoxidation of cyclohexene catalyzed by the vanadium bromoperoxidase from Corallina officinalis[J]. chinese journal of catalysis,2007,28(10):915-918. |
| APA | Yu Yao,Jin Yan,Wu Peichun,&Zhang Wei.(2007).Epoxidation of cyclohexene catalyzed by the vanadium bromoperoxidase from Corallina officinalis.chinese journal of catalysis,28(10),915-918. |
| MLA | Yu Yao,et al."Epoxidation of cyclohexene catalyzed by the vanadium bromoperoxidase from Corallina officinalis".chinese journal of catalysis 28.10(2007):915-918. |
入库方式： OAI收割
来源：大连化学物理研究所
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