Efficient synthesis of benzophenone derivatives in Lewis acid ionic liquids
文献类型:期刊论文
作者 | Li, Changzhi; Liu, Wujun; Zhao, Zongbao (Kent) |
刊名 | catalysis communications
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出版日期 | 2007-11-01 |
卷号 | 8期号:11页码:1834-1837 |
关键词 | ionic liquids Friedel-Crafts reaction acylation benzophenone Lewis acid |
英文摘要 | benzophenone and its derivatives were prepared via friedel-crafts acylation reactions using ionic liquids (ils) of bmimcl-fecl3, bmimcl-aicl(3) and bmimcl-zncl2 as dual catalyst-solvent. among them, bmimcl-fecl3 showed much higher catalytic activity than that observed for the other two ils, and in conventional organic solvents. in these reaction systems, good to excellent yields (up to 97%) of acylation products were obtained in a short reaction time. this method features high yield, a simple product isolation procedure, ils reusability and reduced waste discharge, thus rendering this catalytic system both efficient and environmentally friendly. (c) 2007 elsevier b.v. all rights reserved. |
WOS标题词 | science & technology ; physical sciences |
类目[WOS] | chemistry, physical |
研究领域[WOS] | chemistry |
关键词[WOS] | friedel-crafts acylation ; alkylation ; catalyst ; benzene ; benzoylation ; surfaces ; anisole ; silica ; arenes ; sites |
收录类别 | SCI ; CCR |
语种 | 英语 |
WOS记录号 | WOS:000250256700054 |
公开日期 | 2015-11-17 |
源URL | [http://159.226.238.44/handle/321008/140615] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
推荐引用方式 GB/T 7714 | Li, Changzhi,Liu, Wujun,Zhao, Zongbao . Efficient synthesis of benzophenone derivatives in Lewis acid ionic liquids[J]. catalysis communications,2007,8(11):1834-1837. |
APA | Li, Changzhi,Liu, Wujun,&Zhao, Zongbao .(2007).Efficient synthesis of benzophenone derivatives in Lewis acid ionic liquids.catalysis communications,8(11),1834-1837. |
MLA | Li, Changzhi,et al."Efficient synthesis of benzophenone derivatives in Lewis acid ionic liquids".catalysis communications 8.11(2007):1834-1837. |
入库方式: OAI收割
来源:大连化学物理研究所
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