Structure and electrical conductivity of a novel inorganic solid electrolyte: Na-14.5[Al(PO4)(2)F-2](2.5)[Ti(PO4)(2)F-2](0.5) (NATP)
文献类型：期刊论文
| 作者 | Zhang, Ying; Tian, Peng; Sun, Zhengang; Liu, Ziyu; Zhang, Yangyang; Qu, Lihong; Sang, Shiyun; Liu, Zhongmin |
| 刊名 | solid state communications
 |
| 出版日期 | 2007-02-01 |
| 卷号 | 141期号:7页码:407-411 |
| 关键词 | inorganic solid electrolyte NATP hydrothermal synthesis crystalline structure |
| 英文摘要 | a novel inorganic solid electrolyte with a layered framework structure stable up to 1043 k, na-14.5[al(po4)(2)f-2](2.5)[ti(po4)(2)f-2](0.5)(natp), has been hydrothermally prepared and characterized by single-crystal and powder x-ray diffraction techniques, x-ray fluorescence (xpf) analysis, ir spectroscopic measurement, thermogravimetric and differential thermal analysis (tga and dta). natp crystallizes in the acentric hexagonal space group p3 with a = 10.448(2), b = 10.448(2), c = 6.589(3) angstrom, z = 1, containing a large number of na+ cations in the interlamellar space and the cavities of its framework. there are six different crystallographic na+ cationic sites, in which 8% na(5) and 12% na(6) sites are vacant. electrical conductivity measurements show that na+ cations exhibit a high mobility with two domains for the electrical conductivity versus temperature. (c) 2006 elsevier ltd. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | physics, condensed matter |
| 研究领域[WOS] | physics |
| 关键词[WOS] | ionic-conductivity ; crystal-structure ; conductors ; separation ; framework ; phosphate |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000244423600011 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/140643]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Appl Catalysis Lab, Dalian Inst Chem Phys, Dalian, Liaoning Prov, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Ying,Tian, Peng,Sun, Zhengang,et al. Structure and electrical conductivity of a novel inorganic solid electrolyte: Na-14.5[Al(PO4)(2)F-2](2.5)[Ti(PO4)(2)F-2](0.5) (NATP)[J]. solid state communications,2007,141(7):407-411. |
| APA | Zhang, Ying.,Tian, Peng.,Sun, Zhengang.,Liu, Ziyu.,Zhang, Yangyang.,...&Liu, Zhongmin.(2007).Structure and electrical conductivity of a novel inorganic solid electrolyte: Na-14.5[Al(PO4)(2)F-2](2.5)[Ti(PO4)(2)F-2](0.5) (NATP).solid state communications,141(7),407-411. |
| MLA | Zhang, Ying,et al."Structure and electrical conductivity of a novel inorganic solid electrolyte: Na-14.5[Al(PO4)(2)F-2](2.5)[Ti(PO4)(2)F-2](0.5) (NATP)".solid state communications 141.7(2007):407-411. |
入库方式： OAI收割
来源：大连化学物理研究所
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