Energy Transfer Reactions of Ar(P-3(0,2))+SO2,SOCl2 under the Single Collision Condition
文献类型：期刊论文
| 作者 | Sun Qi1; Gu Yuezhu1; Guo Jingzhong1; Ying Yongjia1; Li Xuechu2; Shen Guanlin2 |
| 刊名 | acta physico-chimica sinica
 |
| 出版日期 | 1995 |
| 卷号 | 11期号:1页码:31-37 |
| 关键词 | Metastable atom Dissociative excitation Vibrational distribution Reaction channel |
| 英文摘要 | dissociative excitation of so2,socl2 through single collision with ar(p-3(0,2)) have been studied by observing so(a - x) emission in the beam apparatus. the nascent vibrational distribution of so(a,v') was determined. a surprisal analysis of the nascent vibrational distribution of so(a) indicated that the precursor molecules dissociation could occur predominately from superexcited states (rydberg-states). the formation rate constants of so(a) have been determined for ar(p-3(0,2))/so2 and ar(p-3(0,2))/socl2 reactions, they are: 4.55x10(-12)cm(3)-molcule(-1).s(-1) and 2.87x10(-12)cm(3).molecule(-1).s(-1), respectively. a comparison between the observed formation rate constants and known total quenching rate constants indicated that dissociative excitation processes are minor exit channels. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, physical |
| 研究领域[WOS] | chemistry |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000207590000007 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/140655]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Shandong Univ, Dept Chem, Jinan 250100, Peoples R China 2.CAS, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Sun Qi,Gu Yuezhu,Guo Jingzhong,et al. Energy Transfer Reactions of Ar(P-3(0,2))+SO2,SOCl2 under the Single Collision Condition[J]. acta physico-chimica sinica,1995,11(1):31-37. |
| APA | Sun Qi,Gu Yuezhu,Guo Jingzhong,Ying Yongjia,Li Xuechu,&Shen Guanlin.(1995).Energy Transfer Reactions of Ar(P-3(0,2))+SO2,SOCl2 under the Single Collision Condition.acta physico-chimica sinica,11(1),31-37. |
| MLA | Sun Qi,et al."Energy Transfer Reactions of Ar(P-3(0,2))+SO2,SOCl2 under the Single Collision Condition".acta physico-chimica sinica 11.1(1995):31-37. |
入库方式： OAI收割
来源：大连化学物理研究所
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